A small-angle neutron scattering study of spherical and wormlike micelles formed by poly(oxyethylene)-based diblock copolymers

被引：52
|
作者：
Hamley, IW [1 ]
Pedersen, JS
Booth, C
Nace, VM
机构：
[1] Univ Leeds, Sch Chem, Leeds LS2 9JT, W Yorkshire, England
[2] Aarhus Univ, Dept Chem, DK-8000 Aarhus C, Denmark
[3] Univ Manchester, Dept Chem, Manchester M13 9PL, Lancs, England
[4] Dow Chem Co USA, Texas Operat, Res & Dev, Freeport, TX 77541 USA
来源：
LANGMUIR | 2001年 / 17卷 / 20期
关键词：
D O I：
10.1021/la010642f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The small-angle neutron scattering study of spherical and wormlike micelles formed by poly(oxyethylene)-based diblock copolymers was discussed. Results showed that the diblock E4B10 formed spherical micelles with a poly(oxybutylene) core over a temperature range of 20 to 60°C. Wormlike micelles were formed at 60° and spherical micelles below 40°. The transition to wormlike micelles was ascribed to a decrease in the coverage of the core by the polyoxyethylene chains at high temperatures.
引用
收藏
页码：6386 / 6388
页数：3
相关论文
共 50 条
  • [21] Small-angle neutron scattering study of microphase separation in thermoassociative copolymers
    Hourdet, D
    L'alloret, F
    Durand, A
    Lafuma, F
    Audebert, R
    Cotton, JP
    MACROMOLECULES, 1998, 31 (16) : 5323 - 5335
  • [22] COMPARATIVE NEUTRON SMALL-ANGLE SCATTERING STUDY OF SMALL SPHERICAL RNA VIRUSES
    JACROT, B
    CHAUVIN, C
    WITZ, J
    NATURE, 1977, 266 (5601) : 417 - 421
  • [23] Small-angle neutron scattering study of the growth behavior, flexibility, and intermicellar interactions of wormlike SDS micelles in NaBr aqueous solutions
    Arleth, L
    Bergström, M
    Pedersen, JS
    LANGMUIR, 2002, 18 (14) : 5343 - 5353
  • [24] Small-Angle Neutron Scattering Studies on the Multilamellae Formed by Mixing Lamella-Forming Cationic Diblock Copolymers with Lipids and Their Interaction with DNA
    Yang, Po-Wei
    Lin, Tsang-Lang
    Liu, I-Ting
    Hu, Yuan
    Jeng, U-Ser
    Gilbert, Elliot Paul
    LANGMUIR, 2016, 32 (07) : 1828 - 1835
  • [25] Geometrical Shape of Micelles Formed by Cationic Dimeric Surfactants Determined with Small-Angle Neutron Scattering
    Bergstrom, L. Magnus
    Garamus, Vasil M.
    LANGMUIR, 2012, 28 (25) : 9311 - 9321
  • [26] Micelles formed from photochemically active amphiphiles: Structural characterization by small-angle neutron scattering
    Schulz, GR
    Martino, DC
    Triolo, R
    Forbes, MDE
    JOURNAL OF MOLECULAR STRUCTURE, 1996, 383 (1-3) : 191 - 196
  • [27] Analysis of conformation of wormlike chains by combination of small-angle X-ray and small-angle neutron scattering
    Hickl, P
    Ballauff, M
    MACROMOLECULAR SYMPOSIA, 1997, 118 : 683 - 692
  • [28] STRUCTURAL STUDY OF RHODOPSIN IN DETERGENT MICELLES BY SMALL-ANGLE NEUTRON-SCATTERING
    OSBORNE, HB
    SARDET, C
    MICHELVILLAZ, M
    CHABRE, M
    JOURNAL OF MOLECULAR BIOLOGY, 1978, 123 (02) : 177 - 206
  • [29] NEUTRON SMALL-ANGLE SCATTERING STUDY OF RHODOPSIN-DEUTERATED DETERGENT MICELLES
    OSBORNE, HB
    CHABRE, M
    SARDET, C
    BIOPHYSICAL JOURNAL, 1978, 21 (03) : A135 - A135
  • [30] TRANSIENT SMALL-ANGLE NEUTRON-SCATTERING OF ALIGNED MICELLES
    KALUS, J
    LINDNER, P
    HOFFMANN, H
    IBEL, K
    MUNCH, C
    SANDER, J
    SCHMELZER, U
    SELBACH, J
    PHYSICA B, 1991, 174 (1-4): : 164 - 169
12345