A small-angle neutron scattering study of spherical and wormlike micelles formed by poly(oxyethylene)-based diblock copolymers

被引：52
作者：
Hamley, IW [1 ]
Pedersen, JS
Booth, C
Nace, VM
机构：
[1] Univ Leeds, Sch Chem, Leeds LS2 9JT, W Yorkshire, England
[2] Aarhus Univ, Dept Chem, DK-8000 Aarhus C, Denmark
[3] Univ Manchester, Dept Chem, Manchester M13 9PL, Lancs, England
[4] Dow Chem Co USA, Texas Operat, Res & Dev, Freeport, TX 77541 USA
来源：
LANGMUIR | 2001年 / 17卷 / 20期
关键词：
D O I：
10.1021/la010642f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The small-angle neutron scattering study of spherical and wormlike micelles formed by poly(oxyethylene)-based diblock copolymers was discussed. Results showed that the diblock E4B10 formed spherical micelles with a poly(oxybutylene) core over a temperature range of 20 to 60°C. Wormlike micelles were formed at 60° and spherical micelles below 40°. The transition to wormlike micelles was ascribed to a decrease in the coverage of the core by the polyoxyethylene chains at high temperatures.
引用
收藏
页码：6386 / 6388
页数：3
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