A solvent-responsive coordination cage

被引：115

作者：

Kilbas, Benan ^{[1
,2
]}

Mirtschin, Sebastian ^{[1
]}

Scopelliti, Rosario ^{[1
]}

Severin, Kay ^{[1
]}

机构：

[1] Ecole Polytech Fed Lausanne, Inst Sci & Ingn Chim, CH-1015 Lausanne, Switzerland

[2] Duzce Univ, Fac Sci, Dept Chem, TR-81620 Duzce, Turkey

来源：

CHEMICAL SCIENCE | 2012年 / 3卷 / 03期

基金：

瑞士国家科学基金会;

关键词：

TRANSLATIONAL ISOMERISM; MOLECULAR SHUTTLES; PEPTIDE ROTAXANES; COMPLEXES; AMIDE;

D O I：

10.1039/c1sc00779c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The solvent-induced structural rearrangement of synthetic supramolecular structures typically requires a pronounced change in solvent polarity. We describe a ruthenium-based coordination cage, whose geometry and topology can be altered dramatically by using two closely related solvents: chloroform and dichloromethane. In chloroform, we observe an octanuclear prismatic cage, whereas a tetranuclear complex is formed in dichloromethane. The basis of this unusual solvent-sensitivity is the incorporation of metallacrown recognition units into a flexible, kinetically labile nanostructure.

引用

页码：701 / 704

页数：4

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