Synthesis and characterization of a new octamolybdate (NH4)4[Mo8O24(C3H2O2)2] • 4H2O

被引：2
作者：
Wang, Shoujiang [1 ]
Mo, Shaofen [2 ]
Liu, Zhen-Gang [3 ]
机构：
[1] Chinese Acad Sci, Qinghai Inst Salt Lakes, Xining 81008, Qinghai Provinc, Peoples R China
[2] Dongguan Univ Technol, Dongguan 523808, Peoples R China
[3] Chinese Acad Sci, Res Ctr Ecoenvironm Sci, Beijing 100085, Peoples R China
来源：
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2012年 / 57卷 / 03期
关键词：
CRYSTAL-STRUCTURE;
D O I：
10.1134/S0036023612030266
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new complex with the formula (NH4)(4)[Mo8O24(C3H2O2)(2)] center dot 4H(2)O (1) has been synthesized and characterized by single crystal X-ray diffraction and infrared spectrum. The complex is small yellow crystal and space group P (1) with a = 9.9869(18) , b = 10.030(19) , c = 10.366(19) , alpha = 91.68(3)A degrees, beta = 98.94(3)A degrees, gamma = 119.37(2)A degrees, V = 887(3) (3), and Z = 1. The complex contains two malonic acid ligands bonded to the gamma-Mo-8 (26) (4-) ions which consist of eight MoO6 edge-sharing octahedral. In this crystal structure, the octamolybdate anion is mutually hydrogen bonded by ammonium ions and water molecules.
引用
收藏
页码：430 / 433
页数：4
相关论文
共 50 条
  • [1] Synthesis, Characterization, Thermal Stability and Decomposition Mechanism of [Ru(C12H8N2)3](C4H2O4)(C4H3O4)(C4H4O4)•4H2O
    Shui, Miao
    Shu, Jie
    Li, Rongsheng
    Song, Yue
    Ren, Yuanlong
    Wang, Qingchun
    ASIAN JOURNAL OF CHEMISTRY, 2012, 24 (11) : 4858 - 4862
  • [2] Tetraammonium diglycinyl-octamolybdate(VI) dihydrate, (NH4)4[(NH3CH2CO)2(Mo8O28)] • 2 H2O
    Liu, G
    Zhang, SW
    Tang, YQ
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2001, 627 (05): : 1077 - 1080
  • [3] Synthesis and characterization of two new ß-octamolybdate complexes [NH4][Y(DMF)5(H2O)3][Mo8O26]•2CH3CN and [NH4][Ce(DMF)7Mo8O26]
    Tian, Cui-Hua
    Sun, Zhen-Gang
    Zhang, Lan-Cui
    Liang, Ha. I-Dong
    Zhu, Zai-Ming
    You, Wan-Sheng
    Gu, Yuan-Peng
    JOURNAL OF COORDINATION CHEMISTRY, 2007, 60 (7-9) : 985 - 993
  • [4] Decavanadate with a novel coordination complex: Synthesis and characterization of (NH4)2[Ni(H2O)5(NH3)]2(V10O28)•4H2O
    Putrevu, Naga Ravikanth
    Doedens, Robert J.
    Khan, M. Ishaque
    INORGANIC CHEMISTRY COMMUNICATIONS, 2013, 38 : 5 - 7
  • [5] Synthesis and structure of [NH4]4H[PMo8VIV4VV2O42].24H2O
    Xu, Y
    Xu, JQ
    Yang, GY
    Wang, TG
    Xing, Y
    Ling, YH
    Jia, HQ
    POLYHEDRON, 1998, 17 (15) : 2441 - 2445
  • [6] Synthesis and crystal structure of [Ni(H2O)6][Ni(H2O)2(C4H2O4)]•4H2O
    Zheng, YQ
    Kong, ZP
    JOURNAL OF COORDINATION CHEMISTRY, 2003, 56 (11) : 967 - 973
  • [7] (NH4)2[Co(H2O)6]2V10O28•4H2O Vs. (NH4)2[Ni(H2O)6]2V10O28•4H2O: Structural, Spectral and Thermal Analyses and Evaluation of Their Antibacterial Activities
    Mamdouh, Ayat-Allah
    Ibrahim, Ahmed B. M.
    Reyad, Nour El-Houda A.
    Elsayed, Tarek R.
    Santos, Isabel Cordeiro
    Paulo, Antonio
    Mahfouz, Refaat M.
    JOURNAL OF CLUSTER SCIENCE, 2023, 34 (03) : 1535 - 1546
  • [8] Synthesis, Structure, and Solubility Studies of a New Arsenato-Polyoxovanadate Cluster Compound: (NH4)4[V12As8O40(H2O)]•4H2O
    Wutkowski, Adam
    Evers, Nils
    Bensch, Wolfgang
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2011, 637 (14-15): : 2205 - 2210
  • [9] Synthesis, characterization and crystal structure of a new β-octamolybdate-supported compound:: [Ni(H2O)(2,2′-bipy)2]2[Mo8O26]•4H2O•2CH3COOH
    Wang, Jingping
    Li, Suzhi
    Zhao, Junwei
    Niu, Jingyang
    INORGANIC CHEMISTRY COMMUNICATIONS, 2006, 9 (06) : 599 - 602
  • [10] Thermal investigation of ammonioborite (NH4)3[B15O20(OH)8] • 4H2O
    Anderson, J. E.
    Bubnova, R. S.
    Filatov, S. K.
    Ugolkov, V. L.
    Britvin, S. N.
    GLASS PHYSICS AND CHEMISTRY, 2009, 35 (02) : 191 - 198
12345