Simple inexpensive boron electrophiles for direct arene borylation

被引:84
作者
Del Grosso, Alessandro [1 ]
Helm, Matthew D. [1 ]
Solomon, Sophia A. [1 ]
Caras-Quintero, Dolores [1 ]
Ingleson, Michael J. [1 ]
机构
[1] Univ Manchester, Dept Chem, Manchester M13 9PL, Lancs, England
基金
英国工程与自然科学研究理事会;
关键词
AROMATIC BORYLATION; H ACTIVATION; SOLAR-CELLS; CATIONS; POLYMERS; BORENIUM; COMPLEXES; ADDUCTS; BORANE; DYES;
D O I
10.1039/c1cc14226g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Electrophilic direct borylation is facilitated, and arene substrate scope enhanced, by using electrophiles derived from inexpensive reagents; specifically an amine, BCl3 and AlCl3.
引用
收藏
页码:12459 / 12461
页数:3
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