Photo-assisted preparation of double isocyanide insertion complexes of η5-cyclopentadienyliron(II) bearing only isocyanide:: the molecular structure of (η5-C5H5)Fe(XylNC)2[C(=NXyl)C(=NXyl)CH3 (XylNC = 2,6-Me2C6H3NC)

被引：4

作者：

Yamamoto, Y ^{[1
]}

Tsuji, M ^{[1
]}

Igoshi, T ^{[1
]}

机构：

[1] Toho Univ, Fac Sci, Dept Chem, Chiba 2740072, Japan

来源：

INORGANICA CHIMICA ACTA | 1999年 / 286卷 / 02期

关键词：

photochemistry; iron complexes; cyclopentadienyl complexes; isocyanide complexes;

D O I：

10.1016/S0020-1693(98)00394-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of eta(5)-C5H5Fe(CO)(2)CH3 (1) with xylyl isocyanide in toluene at reflux gave eta(5)-C5H5Fe(CO)(XylNC)COCH3 (5a) (Xyl = 2,6-(CH3)(2)C6H3), whereas photochemical reaction underwent double insertion of isocyanide molecules into an iron-carbon bond to give a bis-imino type complex (eta(5)-C5H5)Fe(XylNC)(2)[C(=NXyl)C(=NXyl)CH3] (6a), determined by an X-ray analysis. (C) 1999 Elsevier Science S.A. All rights reserved.

引用

页码：233 / 236

页数：4

共 17 条

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