Rational addition of capping groups to the phosphomolybdate Keggin anion [PMo12O40]3- by mild, non-aqueous reductive aggregation

被引：24

作者：

Bakri, Ridla ^{[1
]}

Booth, Andrew ^{[1
]}

Harle, Gavin ^{[1
]}

Middleton, Paul S. ^{[1
]}

Wills, Corinne ^{[1
]}

Clegg, William ^{[1
]}

Harrington, Ross W. ^{[1
]}

Errington, R. John ^{[1
]}

机构：

[1] Newcastle Univ, Sch Chem, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 22期

基金：

英国工程与自然科学研究理事会;

关键词：

BOND-VALENCE PARAMETERS; RAY CRYSTAL-STRUCTURE; HYDROTHERMAL SYNTHESES; BUILDING-BLOCKS; FRAMEWORKS; POLYANION; CLUSTERS; MOLYBDOVANADATE; SYSTEMS; SOLIDS;

D O I：

10.1039/c2cc17670j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Controlled reductive assembly of capped Keggin anions [PMo12O40-(MLm)(n)](3-) has been achieved by reduction of [PMo12O40](3-) with sodium-mercury amalgam in the presence of metal halides, as exemplified by the rational syntheses of mono-capped [PMo12O40{Co(MeCN)(2)}](3-) and bi-capped [PMo12O40(VO)(2)](3-) and [PMo12O40Sb2](3-)

引用

页码：2779 / 2781

页数：3

共 39 条

[11] Hybrid organic-anorganic 1D and 2D frameworks with ε-Keggin polyoxomolybdates as building blocks
Dolbecq, A
Mialane, P
Lisnard, L
Marrot, J
Sécheresse, F
[J]. CHEMISTRY-A EUROPEAN JOURNAL, 2003, 9 (12) : 2914 - 2920
[12] Hybrid Organic-Inorganic Polyoxometalate Compounds: From Structural Diversity to Applications
Dolbecq, Anne
Dumas, Eddy
Mayer, Cedric R.
Mialane, Pierre
[J]. CHEMICAL REVIEWS, 2010, 110 (10) : 6009 - 6048
[13] Errington R. J., 2003, COMPREHENSIVE COORDI, V2, P759
[14] Errington R. J., 2001, POLYOXOMETALATE MOL, P1
[15] Errington RJ, 2003, NATO SCI SER II MATH, V98, P55
[16] Novel Doped Tungstovanadate and Molybdovanadate with Bi-antimony-Capped Keggin Structure
Han, Zhangang
Wu, Jingjing
Gao, Yuanzhe
Zhai, Xueliang
[J]. AUSTRALIAN JOURNAL OF CHEMISTRY, 2011, 64 (02) : 197 - 205
[17] Synthesis, spectroscopic characterization and X-ray crystal structure of vanadylpolymolybdophosphates with monocapped Keggin polyanion [PMo5V7O40(VO)]7-
Hu, CJ
Duan, CY
Liu, YJ
Lu, CS
Ren, XM
Meng, QJ
[J]. POLYHEDRON, 2001, 20 (17) : 2117 - 2121
[18] Kato R., 1980, J AM CHEM SOC, V102, P6572
[19] KHAN MI, 1993, INORG CHIM ACTA, V212, P199
[20] PROTONATION SITES IN A HETEROPOLYVANADATE OF PHOSPHORUS - X-RAY CRYSTAL-STRUCTURE OF (ME3NH)4(NH4)[H4PV14O42]
KHAN, MI
ZUBIETA, J
TOSCANO, P
[J]. INORGANICA CHIMICA ACTA, 1992, 193 (01) : 17 - 20

← 1 2 3 4 →