Synthesis and characterization of a furan-based self-healing polymer

被引：27
作者：
Ryu, Yeon Sung [1 ]
Oh, Kyung Wha [2 ]
Kim, Seong Hun [1 ]
机构：
[1] Hanyang Univ, Dept Organ & Nano Engn, 17 Haengdang Dong, Seoul 04763, South Korea
[2] Chung Ang Univ, Dept Fash Design, 4726 Seodongdae Ro, Anseong 17546, Gyeonggi, South Korea
来源：
MACROMOLECULAR RESEARCH | 2016年 / 24卷 / 10期
基金：
新加坡国家研究基金会;
关键词：
self-healing; furan based polymer; diels-alder reaction; biopolyurethane; enzymatic degradation; POLYESTERS;
D O I：
10.1007/s13233-016-4122-5
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The extensive researches of self-healing polymer have been carried out for various applications in industrial fields. In this research, bio-based self-healing polymer was prepared using a cross-linking mechanism between polybutylene furanoate (PBF) and bismaleimide (BM) by Diels-Alder reactions, and it was blended with bio-based polyurethane (BPU) to improve the liquidity, elasticity, and mechanical properties. These self-healing polymer and BPU blended elastomer were made with different ratios of PBF, BM, and BPU. PBF-BM polymer has 6:1, 8:1, and 10:1 of PBF: BM ratios. Each polymer and BPU constitutes self-healing elastomer with 1:1, 1:1.5, and 1:2 ratios. Properties and self-healing ability of these elastomers were investigated by thermal, mechanical, and morphological analysis. On average, 6:1 of PBF: BM ratio shows the outstanding self-healing efficiency and 1:2 of PBF-BM polymer: BPU ratio has the highest mechanical properties with maintain its self-healing ability. Overall results indicated that BPU is a good reinforcement of the furan-based self-healing polymer with improving the self-healing ability and eco-friendly performance.
引用
收藏
页码：874 / 880
页数：7
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