Direct Access to Parent Amido Complexes of Rhodium and Iridium through N?H Activation of Ammonia

被引：56

作者：

Mena, Inmaculada ^{[1
]}

Casado, Miguel A. ^{[1
]}

Garcia-Orduna, Pilar ^{[1
]}

Polo, Victor ^{[2
]}

Lahoz, Fernando J. ^{[1
]}

Fazal, Atif ^{[3
]}

Oro, Luis A. ^{[1
,3
]}

机构：

[1] Univ Zaragoza, ISQCH, CSIC, E-50009 Zaragoza, Spain

[2] Univ Zaragoza, Dept Quim Fis, E-50009 Zaragoza, Spain

[3] King Fahd Univ Petr & Minerals, Ctr Refining & Petrochem, Dhahran 31261, Saudi Arabia

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 49期

关键词：

amido complexes; ammonia; iridium; N?H activation; rhodium; OXIDATIVE ADDITION; H ACTIVATION; STRUCTURAL-CHARACTERIZATION; REDUCTIVE ELIMINATION; REACTIVITY; CLEAVAGE; DIHYDROGEN; CHEMISTRY; AMINES; BONDS;

D O I：

10.1002/anie.201104745

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Simplicity! A direct entry to amido rhodium and iridium complexes was easily achieved by reaction of gaseous ammonia with alkoxo-bridged precursors under very mild conditions. This new approach allowed the high-yield access for the first time to elusive [Rh-NH 2] complexes. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：11735 / 11738

页数：4

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