Zn(II) and Cu(II) tetrakis(diarylamine)phthalocyanines as hole-transporting materials for perovskite solar cells

被引：12

作者：

Klipfel, Nadja ^{[1
]}

Xia, Jianxing ^{[1
]}

Culik, Pavel ^{[1
]}

Orlandi, Simonetta ^{[2
]}

Cavazzini, Marco ^{[2
]}

Shibayama, Naoyuki ^{[3
]}

Kanda, Hiroyuki ^{[1
]}

Igci, Cansu ^{[1
]}

Li, Wei ^{[4
]}

Cheng, Yi-Bing ^{[4
]}

Jankauskas, Vygintas ^{[5
]}

Genevicius, Kristijonas ^{[5
]}

Asiri, Abdullah M. ^{[6
]}

Momblona, Cristina ^{[1
]}

Rakstys, Kasparas ^{[5
]}

Pozzi, Gianluca ^{[2
]}

Nazeeruddin, Mohammad Khaja ^{[1
,7
]}

机构：

[1] Ecole Polytech Fed Lausanne, Inst Chem Sci & Engn, Grp Mol Engn Funct Mat, Rue Ind 17, CH-1950 Sion, Switzerland

[2] CNR Inst Chem Sci & Technol Giulio Natta CNR SCIT, UOS Golgi, Via Golgi 19, I-20133 Milan, Italy

[3] Toin Univ Yokohama, Dept Biomed Engn, Aoba Ku, Yokohama, Kanagawa, Japan

[4] Xianhu Hydrogen Valley, Foshan Xianhu Lab Adv Energy Sci & Technol Guangd, Foshan, Peoples R China

[5] Kaunas Univ Technol, Dept Organ Chem, Radvilenu Pl 19, LT-50254 Kaunas, Lithuania

[6] King Abdulaziz Univ, Ctr Excellence Adv Mat Res CEAMR, POB 80203, Jeddah 21589, Saudi Arabia

[7] City Univ Hong Kong, Dept Mat Sci & Engn, Kowloon, Hong Kong, Peoples R China

来源：

MATERIALS TODAY ENERGY | 2022年 / 29卷

基金：

欧盟地平线“2020”; 瑞士国家科学基金会;

关键词：

Zn-phthalocyanines; Spin-coating; Diarylamine; Functionalization; Alkoxy chains; HIGHLY EFFICIENT; CHAIN LENGTH; PHTHALOCYANINE; DEGRADATION; PORPHYRIN; LAYER;

D O I：

10.1016/j.mtener.2022.101110

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Finding new hole-transporting materials (HTMs) suitable for replacing the state-of-the-art spiro-OMe-TAD is still challenging. In this work, newly synthesized diarylamine-substituted metal phthalocyanines (MPcs, M 1/4 Zn(II) or Cu(II)) functionalized with either linear or branched alkoxy chains are evaluated as HTMs in perovskite solar cells. Both the nature of the alkoxy chains and that of the coordinated metal species were found to influence the functional properties of the new MPcs. In particular, devices based on a ZnPc featuring four n-butoxy side chains exhibited the highest power conversion efficiencies (PCEs). A PCE of 20.00% was reached for triple cation perovskite devices, and a PCE up to 20.18% could be achieved for double cation devices. (C) 2022 The Authors. Published by Elsevier Ltd.

引用

页数：11

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