A Neutral Gallium(I) N-Heterocyclic Carbene Analogue: Synthesis, Characterization and Theoretical Analysis

被引：20

作者：

Choong, Sam L. ^{[1
]}

Woodul, William D. ^{[1
]}

Stasch, Andreas ^{[1
]}

Schenk, Christian ^{[1
]}

Jones, Cameron ^{[1
]}

机构：

[1] Monash Univ, Sch Chem, Melbourne, Vic 3800, Australia

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 2011年 / 64卷 / 08期

基金：

澳大利亚研究理事会;

关键词：

CHEMISTRY; COMPLEXES; ELEMENTS; ANIONS;

D O I：

10.1071/CH11193

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The six-membered N-heterocyclic gallium(I) compound [:Ga((But)Nacnac)] ((But)Nacnac(-)=[{N(Dip)C(Bu-t)}(2)CH](-), Dip = 2,6-diisopropylphenyl) has been synthesized, crystallographically characterized, and its electronic properties analyzed using density functional theory. For purposes of comparison, the isoelectronic cationic germanium(II) complex, [:Ge((But)Nacnac)][Al{OC(CF3)(3)}(4)], has been prepared and structurally authenticated.

引用

页码：1173 / 1176

页数：4

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