A Neutral Gallium(I) N-Heterocyclic Carbene Analogue: Synthesis, Characterization and Theoretical Analysis

被引：20
|
作者：
Choong, Sam L. [1 ]
Woodul, William D. [1 ]
Stasch, Andreas [1 ]
Schenk, Christian [1 ]
Jones, Cameron [1 ]
机构：
[1] Monash Univ, Sch Chem, Melbourne, Vic 3800, Australia
来源：
AUSTRALIAN JOURNAL OF CHEMISTRY | 2011年 / 64卷 / 08期
基金：
澳大利亚研究理事会;
关键词：
CHEMISTRY; COMPLEXES; ELEMENTS; ANIONS;
D O I：
10.1071/CH11193
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The six-membered N-heterocyclic gallium(I) compound [:Ga((But)Nacnac)] ((But)Nacnac(-)=[{N(Dip)C(Bu-t)}(2)CH](-), Dip = 2,6-diisopropylphenyl) has been synthesized, crystallographically characterized, and its electronic properties analyzed using density functional theory. For purposes of comparison, the isoelectronic cationic germanium(II) complex, [:Ge((But)Nacnac)][Al{OC(CF3)(3)}(4)], has been prepared and structurally authenticated.
引用
收藏
页码：1173 / 1176
页数：4
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