A Neutral Gallium(I) N-Heterocyclic Carbene Analogue: Synthesis, Characterization and Theoretical Analysis

被引:20
|
作者
Choong, Sam L. [1 ]
Woodul, William D. [1 ]
Stasch, Andreas [1 ]
Schenk, Christian [1 ]
Jones, Cameron [1 ]
机构
[1] Monash Univ, Sch Chem, Melbourne, Vic 3800, Australia
基金
澳大利亚研究理事会;
关键词
CHEMISTRY; COMPLEXES; ELEMENTS; ANIONS;
D O I
10.1071/CH11193
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The six-membered N-heterocyclic gallium(I) compound [:Ga((But)Nacnac)] ((But)Nacnac(-)=[{N(Dip)C(Bu-t)}(2)CH](-), Dip = 2,6-diisopropylphenyl) has been synthesized, crystallographically characterized, and its electronic properties analyzed using density functional theory. For purposes of comparison, the isoelectronic cationic germanium(II) complex, [:Ge((But)Nacnac)][Al{OC(CF3)(3)}(4)], has been prepared and structurally authenticated.
引用
收藏
页码:1173 / 1176
页数:4
相关论文
共 50 条
  • [1] Experimental Charge Density Analysis of a Gallium(I) N-Heterocyclic Carbene Analogue
    Overgaard, Jacob
    Jones, Cameron
    Dange, Deepak
    Patts, James A.
    INORGANIC CHEMISTRY, 2011, 50 (17) : 8418 - 8426
  • [2] Synthesis and characterisation of anionic and neutral gallium(I) N-heterocyclic carbene analogues
    Dange, Deepak
    Choong, Sam L.
    Schenk, Christian
    Stasch, Andreas
    Jones, Cameron
    DALTON TRANSACTIONS, 2012, 41 (31) : 9304 - 9315
  • [3] Synthesis and Crystal Structures of Anionic Gallium(II) and Gallium(III) Heterocyclic Compounds Derived from a Gallium(I) N-Heterocyclic Carbene Analogue
    Cameron Jones
    David P. Mills
    Eric Rivard
    Andreas Stasch
    William D. Woodul
    Journal of Chemical Crystallography, 2010, 40 : 965 - 969
  • [4] Synthesis and Crystal Structures of Anionic Gallium(II) and Gallium(III) Heterocyclic Compounds Derived from a Gallium(I) N-Heterocyclic Carbene Analogue
    Jones, Cameron
    Mills, David P.
    Rivard, Eric
    Stasch, Andreas
    Woodul, William D.
    JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2010, 40 (11) : 965 - 969
  • [5] Oxidation reactions of an anionic gallium(I) N-heterocyclic carbene analogue with group 16 compounds
    Baker, RJ
    Jones, C
    Kloth, M
    DALTON TRANSACTIONS, 2005, (12) : 2106 - 2110
  • [6] Extending the series: Synthesis and characterization of a dicationic N-heterocyclic selenium carbene analogue
    Dutton, Jason L.
    Tuononen, Heikki M.
    Jennings, Michael C.
    Ragogna, Paul J.
    Journal of the American Chemical Society, 2006, 128 (39): : 12624 - 12625
  • [7] Extending the series: Synthesis and characterization of a dicationic N-heterocyclic selenium carbene analogue
    Dutton, Jason L.
    Tuononen, Heikki M.
    Jennings, Michael C.
    Ragogna, Paul J.
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (39) : 12624 - 12625
  • [8] Oxidative addition of an imidazolium cation to an anionic gallium(I) N-heterocyclic carbene analogue:: Synthesis and characterisation of novel gallium hydride complexes
    Jones, Cameron
    Mills, David P.
    Rose, Richard P.
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2006, 691 (13) : 3060 - 3064
  • [9] The reactivity of an anionic gallium N-heterocyclic carbene analogue with a solution stable digermene
    Rupar, Paul A.
    Jennings, Michael C.
    Baines, Kim M.
    CANADIAN JOURNAL OF CHEMISTRY, 2007, 85 (02) : 141 - 147
  • [10] Synthesis and structural characterization of N-heterocyclic carbene gold(I) complexes
    de Frémont, P
    Scott, NM
    Stevens, ED
    Nolan, SP
    ORGANOMETALLICS, 2005, 24 (10) : 2411 - 2418