Oxidation of benzyl alcohols by dimethyldioxirane. The question of concerted versus stepwise mechanisms probed by kinetic isotope effects

被引：14
作者：
Angelis, YS [1 ]
Hatzakis, NS [1 ]
Smonou, I [1 ]
Orfanopoulos, M [1 ]
机构：
[1] Univ Crete, Dept Chem, Iraklion 71409, Crete, Greece
来源：
TETRAHEDRON LETTERS | 2001年 / 42卷 / 22期
关键词：
dioxiranes; isotope effects; mechanisms;
D O I：
10.1016/S0040-4039(01)00539-1
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The primary and beta -secondary kinetic isotope effects in the oxidation of secondary alcohols with dimethyl dioxirane were measured. The substantial primary and the absence of a P-secondary kinetic isotope effect support a concerted mechanism for the title reaction. (C) 2001 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：3753 / 3756
页数：4
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