Photochemical degradation study of an epoxy material by IR-ATR spectroscopy

被引：67
作者：
Monney, L
Belali, R
Vebrel, J
Dubois, C
Chambaudet, A
机构：
[1] Univ Franche Comte, Equipe Accueil Microanal Mat 473, Lab Microanal Nucl, F-25030 Besancon, France
[2] Univ Franche Comte, CNRS, URA 772, Phys Mol Lab, F-25030 Besancon, France
[3] Univ Franche Comte, Lab Chim & Electrochim Mol, F-25030 Besancon, France
来源：
POLYMER DEGRADATION AND STABILITY | 1998年 / 62卷 / 02期
关键词：
D O I：
10.1016/S0141-3910(98)00018-4
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Photochemical degradation of an epoxy resin (DGEBA) cross-linked with methyltetrahydrophthalic anhydride (MTHPA) was studied by means of FT-IR spectroscopy with attenuated total reflection (ATR). Using an identified absorption band as a reference, we obtained spectra that allowed us to detect the organic matrix chemical modifications during photo-aging of the irradiated surface. Besides the fact that the thickness of the photo-oxidized layer can be estimated, molecular changes confirm some mechanisms which have been proposed in other literature. (C) 1998 Elsevier Science Limited. All rights reserved.
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页码：353 / 359
页数：7
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