Porous structure design of carbon xerogels for advanced supercapacitor

被引：49

作者：

Liu, Xichuan ^{[1
]}

Li, Shaomin ^{[1
]}

Mi, Rui ^{[1
]}

Mei, Jun ^{[1
]}

Liu, Li-Min ^{[2
]}

Cao, Liujun ^{[1
]}

Lau, Woon-Ming ^{[1
,2
]}

Liu, Hao ^{[1
]}

机构：

[1] China Acad Engn Phys, Chengdu Dev Ctr Sci & Technol, Chengdu Green Energy & Green Mfg Technol R&D Ctr, Chengdu, Sichuan, Peoples R China

[2] Beijing Computat Sci Res Ctr, Beijing 100084, Peoples R China

来源：

APPLIED ENERGY | 2015年 / 153卷

基金：

国家高技术研究发展计划(863计划);

关键词：

Nitrogen-doped; Hierarchically porous structures; Ultrahigh surface area; Supercapacitor; DOUBLE-LAYER CAPACITORS; OXYGEN REDUCTION REACTION; MELAMINE-RESORCINOL-FORMALDEHYDE; NITROGEN-DOPED GRAPHENE; HIGH-SURFACE-AREA; ELECTROCHEMICAL PERFORMANCE; ACTIVATED CARBON; MESOPOROUS CARBONS; FACILE SYNTHESIS; AEROGELS;

D O I：

10.1016/j.apenergy.2015.01.141

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

A porous carbon electrode incorporating considerations both heteroatom doping and pore structure design with: combination of melamine and PEO-PPO-PEO (polyethylene oxide-polypropylene oxide-polyethylene oxide) micelles for the nitrogen-doping and optimization the micron-duct formation; integration of CO2-etching into the carbonization process for the formation of abundant micropores. The structure of these nitrogen-doped carbon xerogels (NCXs) are indeed comprised of a multi-scaled pores having nano-porous carbon in a network of micron-size percolated hollow-channels. The resulted material has an ultrahigh surface area of 4279 m(2) g(-1) when used as electrode for supercapacitor, which deliver a high specific capacitance of 271 F g(-1) with excellent cycle stability and good rate capability. (C) 2015 Elsevier Ltd. All rights reserved.

引用

页码：32 / 40

页数：9

共 56 条

[31] Structural characterization of N-containing activated carbon fibers prepared from a low softening point petroleum pitch and a melamine resin [J].