Rechargeable hydrogen storage in nanostructured mixtures of hydrogenated carbon and lithium hydride

被引:48
作者
Ichikawa, T
Fujii, H
Isobe, S
Nabeta, K
机构
[1] Hiroshima Univ, Ctr Math Sci, N BARD, Higashihiroshima 7398626, Japan
[2] Hiroshima Univ, Grad Sch Adv Sci Matter, Higashihiroshima 7398530, Japan
关键词
D O I
10.1063/1.1946188
中图分类号
O59 [应用物理学];
学科分类号
摘要
A hydrogen storage ability caused by the interaction between nanostructured carbon (CnanoHx) and lithium hydride (LiH) is demonstrated, which should be recognized as Li-C-H system in the H-storage materials. Especially, the 2: 1 mixture of CnanoHx and LiH exhibited promising hydrogen storage properties with a rechargeable hydrogen capacity of more than 4 mass% below 350 degrees C, preserving the nanostructural feature in the mixture even after hydrogen release. On the other hand, the 1: 2 and 1: 1 mixtures exhibited the crystal growth of Li2C2 after hydrogen desorption, leading to poorer hydrogen rechargeability. (c) 2005 American Institute of Physics.
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页码:1 / 3
页数:3
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