Heterometal-Embedded Organic Conjugate Frameworks from Alternating Monomeric Iron and Cobalt Metalloporphyrins and Their Application in Design of Porous Carbon Catalysts

被引：233
作者：
Lin, Qipu [1 ]
Bu, Xianhui [2 ]
Kong, Aiguo [1 ]
Mao, Chengyu [1 ]
Bu, Fei [1 ]
Feng, Pingyun [1 ]
机构：
[1] Univ Calif Riverside, Dept Chem, Riverside, CA 92521 USA
[2] Calif State Univ Long Beach, Dept Chem & Biochem, Long Beach, CA 90840 USA
来源：
ADVANCED MATERIALS | 2015年 / 27卷 / 22期
关键词：
covalent organic frameworks; heterometals; non-precious metal catalysts; oxygen reduction reaction; OXYGEN REDUCTION REACTION; HIGH-PERFORMANCE ELECTROCATALYSTS; METAL-FREE ELECTROCATALYSTS; HIGH-SURFACE-AREA; POLYMER NETWORKS; GRAPHENE; CLUSTERS; COMPLEXES;
D O I：
10.1002/adma.201500727
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The use of an alternately conjugated networking method to prepare the first porous heterometalloporphyrinic frameworks with ordered alternation of Fe and Co moieties is presented. Subsequent carbonization gives an Fe and Co co-embedded porous carbon composite with a very high activity and remarkable electrochemical stability for oxygen reduction reaction in both alkaline and acidic electrolytes. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：3431 / 3436
页数：6
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