Heterometal-Embedded Organic Conjugate Frameworks from Alternating Monomeric Iron and Cobalt Metalloporphyrins and Their Application in Design of Porous Carbon Catalysts

被引：234

作者：

Lin, Qipu ^{[1
]}

Bu, Xianhui ^{[2
]}

Kong, Aiguo ^{[1
]}

Mao, Chengyu ^{[1
]}

Bu, Fei ^{[1
]}

Feng, Pingyun ^{[1
]}

机构：

[1] Univ Calif Riverside, Dept Chem, Riverside, CA 92521 USA

[2] Calif State Univ Long Beach, Dept Chem & Biochem, Long Beach, CA 90840 USA

来源：

ADVANCED MATERIALS | 2015年 / 27卷 / 22期

关键词：

covalent organic frameworks; heterometals; non-precious metal catalysts; oxygen reduction reaction; OXYGEN REDUCTION REACTION; HIGH-PERFORMANCE ELECTROCATALYSTS; METAL-FREE ELECTROCATALYSTS; HIGH-SURFACE-AREA; POLYMER NETWORKS; GRAPHENE; CLUSTERS; COMPLEXES;

D O I：

10.1002/adma.201500727

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The use of an alternately conjugated networking method to prepare the first porous heterometalloporphyrinic frameworks with ordered alternation of Fe and Co moieties is presented. Subsequent carbonization gives an Fe and Co co-embedded porous carbon composite with a very high activity and remarkable electrochemical stability for oxygen reduction reaction in both alkaline and acidic electrolytes. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：3431 / 3436

页数：6

共 52 条

[1]

Beaudoin D, 2013, NAT CHEM, V5, P830, DOI [10.1038/nchem.1730, 10.1038/NCHEM.1730]

[2] Targeted Synthesis of a Porous Aromatic Framework with High Stability and Exceptionally High Surface Area [J].

Ben, Teng ;

Ren, Hao ;

Ma, Shengqian ;

Cao, Dapeng ;

Lan, Jianhui ;

Jing, Xiaofei ;

Wang, Wenchuan ;

Xu, Jun ;

Deng, Feng ;

Simmons, Jason M. ;

Qiu, Shilun ;

Zhu, Guangshan .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (50) :9457-9460

[3] Thiophene-based covalent organic frameworks [J].

Bertrand, Guillaume H. V. ;

Michaelis, Vladimir K. ;

Ong, Ta-Chung ;

Griffin, Robert G. ;

Dinca, Mircea .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2013, 110 (13) :4923-4928

[4] Heterometallic Modular Metal-Organic 3D Frameworks Assembled via New Tris-β-Diketonate Metalloligands: Nanoporous Materials for Anion Exchange and Scaffolding of Selected Anionic Guests [J].

Carlucci, Lucia ;

Ciani, Gianfranco ;

Maggini, Simona ;

Proserpio, Davide M. ;

Visconti, Marco .

CHEMISTRY-A EUROPEAN JOURNAL, 2010, 16 (41) :12328-12341

[5] CMPs as Scaffolds for Constructing Porous Catalytic Frameworks: A Built-in Heterogeneous Catalyst with High Activity and Selectivity Based on Nanoporous Metalloporphyrin Polymers [J].

Chen, Long ;

Yang, Yong ;

Jiang, Donglin .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (26) :9138-9143

[6] A review on non-precious metal electrocatalysts for PEM fuel cells [J].

Chen, Zhongwei ;

Higgins, Drew ;

Yu, Aiping ;

Zhang, Lei ;

Zhang, Jiujun .

ENERGY & ENVIRONMENTAL SCIENCE, 2011, 4 (09) :3167-3192

[7] Intrinsic Relationship between Enhanced Oxygen Reduction Reaction Activity and Nanoscale Work Function of Doped Carbons [J].

Cheon, Jae Yeong ;

Kim, Jong Hun ;

Kim, Jae Hyung ;

Goddeti, Kalyan C. ;

Park, Jeong Young ;

Joo, Sang Hoon .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (25) :8875-8878

[8] Ordered mesoporous porphyrinic carbons with very high electrocatalytic activity for the oxygen reduction reaction [J].

Cheon, Jae Yeong ;

Kim, Taeyoung ;

Choi, YongMan ;

Jeong, Hu Young ;

Kim, Min Gyu ;

Sa, Young Jin ;

Kim, Jaesik ;

Lee, Zonghoon ;

Yang, Tae-Hyun ;

Kwon, Kyungjung ;

Terasaki, Osamu ;

Park, Gu-Gon ;

Adzic, Radoslav R. ;

Joo, Sang Hoon .

SCIENTIFIC REPORTS, 2013, 3

[9] Highly Active Porous Carbon-Supported Nonprecious Metal-N Electrocatalyst for Oxygen Reduction Reaction in PEM Fuel Cells [J].

Choi, Ja-Yeon ;

Hsu, Ryan S. ;

Chen, Zhongwei .

JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (17) :8048-8053

[10] Rationally synthesized two-dimensional polymers [J].

Colson, John W. ;

Dichtel, William R. .

NATURE CHEMISTRY, 2013, 5 (06) :453-465

← 1 2 3 4 5 6 →