Development of spinel opaque glazes for ceramic tiles

被引:18
作者
Cai, Jingpei [1 ]
Lv, Ming [1 ]
Guan, Kang [1 ]
Sun, Qian [1 ]
Peng, Cheng [1 ]
Wu, Jianqing [1 ]
Liu, Yong [2 ]
机构
[1] South China Univ Technol, Sch Mat Sci & Engn, Guangzhou 510640, Guangdong, Peoples R China
[2] South China Agr Univ, Sch Phys, Guangzhou 510640, Guangdong, Peoples R China
基金
中国国家自然科学基金;
关键词
Microstructure; Fast-firing; Opaque glazes; Spinel; FLOOR-TILES; GLASS-CERAMICS; CRYSTALLIZATION; MICROSTRUCTURE; MECHANISM; ZIRCON; SYSTEM; ADDITIVES; BEHAVIOR; FRITS;
D O I
10.1016/j.jeurceramsoc.2017.07.037
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The feasibility of developing fast-firing opaque wall tile glazes obtained from zircon-free frits was studied. The structural and morphological characteristics of the glazes were determined by differential scanning calorimetry, an optical dilatometer, X-ray diffraction and scanning electron microscopy. The studied glaze was characterized by a high whiteness value L* greater than 94, very low values of a* and b* which is about -0.65 and 0.01, respectively, and a high gloss value above 98%. The opaque effect is due to the presence of spine! crystals with a size range of 0.2-1.0 mu m, which is formed by devitrification during fast-firing. The Vickers micro-hardness of the studied glaze is higher than the one of the commercial zircon based glass-ceramic glazes. This type of frit can be an alternative one for fabricating opaque ceramic glazes.
引用
收藏
页码:297 / 302
页数:6
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