Hydrogen isotope separation by gas chromatography using Pd-Pt alloy

被引:25
作者
Watanabe, K [1 ]
Matsuyama, M [1 ]
Kobayashi, T [1 ]
Shu, WM [1 ]
机构
[1] Toyama Univ, Hydrogen Isotope Res Ctr, Toyama 930, Japan
关键词
D O I
10.1016/S0920-3796(98)00160-4
中图分类号
TL [原子能技术]; O571 [原子核物理学];
学科分类号
0827 ; 082701 ;
摘要
A new type of chromatography for hydrogen isotope separation was developed employing a Pd-Pt alloy (8 at.% Pt) as functional material. It could separate a H(2)-D(2) mixture into H(2) and D(2) in the temperature range of 274-297 K in a short time with simple operation procedures without introducing ally replacement gas. An elusion mechanism plays an important role in the separation, and a replacement mechanism and/or a mixing effect may also be participating. A good separation can be expected under conditions of moderate operation temperature, a high carrier gas pressure and a slow flow rate. The new chromatography has potential for application in isotope separation systems for thermonuclear fusion devices. (C) 1998 Elsevier Science S.A. All rights reserved.
引用
收藏
页码:1001 / 1008
页数:8
相关论文
共 14 条
  • [1] Glueckauf E., 1958, P INT S ISOTOPE SEPA, P210
  • [2] METAL HYDRIDE BASED ISOTOPE-SEPARATION - LARGE-SCALE OPERATIONS
    HOREN, AS
    LEE, MW
    [J]. FUSION TECHNOLOGY, 1992, 21 (02): : 282 - 286
  • [3] KOBAYASHI T, 1995, ANN REP HYDROGEN ISO, V15, P33
  • [4] KOBAYASHI T, 1994, ANN REPORT HYDROGEN, V14, P97
  • [5] KONISHI T, 1994, J PLASMA FUSION RES, V70, P16
  • [6] LASSER R, 1995, FUSION TECHNOL, V28, P681
  • [7] LATTICE CONSTANTS + THERMODYNAMIC PARAMETERS OF HYDROGEN-PLATINUM-PALLADIUM + DEUTERIUM-PLATINUM-PALLADIUM SYSTEMS
    MAELAND, A
    FLANAGAN, TB
    [J]. JOURNAL OF PHYSICAL CHEMISTRY, 1964, 68 (06) : 1419 - &
  • [8] Routine operation of the gas chromatographic isotope separation system of the Tritium Laboratory Karlsruhe
    Neffe, G
    Besserer, U
    Dehne, J
    Hutter, E
    Kissel, H
    Penzhorn, RD
    Wendel, J
    Brunnader, H
    [J]. FUSION ENGINEERING AND DESIGN, 1998, 39-40 : 987 - 993
  • [9] RAE HK, 1978, ACS S SER
  • [10] GAS-CHROMATOGRAPHIC SEPARATION OF HYDROGEN ISOTOPES ON MOLECULAR-SIEVES
    VOGD, R
    RINGEL, H
    HACKFORT, H
    SCHOBER, T
    DIEKER, C
    [J]. FUSION TECHNOLOGY, 1988, 14 (02): : 574 - 578