Synthesis and characterization of a novel latent ring-opening metathesis polymerization catalyst

被引：2

作者：

Sherstobitov, Ivan A. ^{[1
]}

Kiselev, Stanislav A. ^{[1
]}

Lyapkov, Alex A. ^{[1
]}

Yusubov, Mekhman S. ^{[1
]}

Zhdankin, Viktor V. ^{[1
,2
]}

Yu, Bao-Yi ^{[3
]}

Verpoort, Francis ^{[1
,4
]}

机构：

[1] Natl Res Tomsk Polytech Univ, Tomsk 634050, Russia

[2] Univ Minnesota, Dept Chem & Biochem, Duluth, MN 55812 USA

[3] Beijing Univ Agr, Coll Biol Sci Engn, Key Lab Urban Agr North China, Minist Agr, Beijing 102206, Peoples R China

[4] Wuhan Univ Technol, Lab Organometall Catalysis & Ordered Mat, State Key Lab Adv Technol Mat Synth & Proc, Wuhan 430070, Peoples R China

来源：

TETRAHEDRON LETTERS | 2021年 / 84卷

关键词：

Ruthenium catalyst; Olefin metathesis-controlled initiation; 2; 5-disubstituted; 1; 3; 4-oxadiazoles; Ring-opening metathesis polymerization; Latent catalysts; OLEFIN; COMPLEXES; ROMP;

D O I：

10.1016/j.tetlet.2021.153451

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis and characterization of a novel latent ruthenium catalyst bearing a chelate ligand containing an oxadiazole fragment for the olefin metathesis are described. The main advantages of the utilization of this ligand are the straightforwardness of preparation, mild reaction conditions, and availability of the feedstock. Preliminary study of the catalytic activity of the Ru complex for metathesis reactions demonstrated its inactive nature for the ring-closing metathesis (RCM), but an excellent thermo-switchability for the ring-opening metathesis polymerization of norbornene. (c) 2021 Elsevier Ltd. All rights reserved.

引用

页数：4

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