Determination of Copper(II) Through Anodic Stripping Voltammetry in Tartrate Buffer Using an Antimony Film Screen-printed Carbon Electrode

被引：13
作者：
Bobrowski, Andrzej [1 ]
Maczuga, Mariola [1 ]
Krolicka, Agnieszka [1 ]
Konstanteli, Evangelia [2 ]
Sakellaropoulou, Chrysavgi [2 ]
Economou, Anastasios [2 ]
机构：
[1] AGH Univ Sci & Technol, Fac Mat Sci & Ceram, Dept Bldg Mat Technol, Al Mickiewicza 30, PL-30059 Krakow, Poland
[2] Univ Athens, Dept Chem, Analyt Chem Lab, Athens, Greece
来源：
ANALYTICAL LETTERS | 2017年 / 50卷 / 18期
关键词：
Antimony film screen-printed carbon electrode (SbF-SPE); copper determination; differential pulse anodic stripping voltammetry (DP-ASV); limestone; potassium hydrogen tartrate; TRACE HEAVY-METALS; PASTE ELECTRODES; ELECTROCHEMICAL DETERMINATION; GOLD ELECTRODES; WASTE-WATER; SENSORS; BISMUTH; PB(II); FIELD; LEAD;
D O I：
10.1080/00032719.2017.1319850
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
The voltammetric performance of an in situ plated antimony film screen-printed carbon electrode in hydrochloric acid, acetate buffer, and tartrate buffer was evaluated for the detection of copper(II) with differential pulse anodic stripping voltammetry. The tartrate buffer was superior, providing high sensitivity and good separation of copper and antimony stripping peaks. The analytical conditions for the determination of copper(II) were optimized. The detection limit was estimated to be 0.14 mu gL(-1) copper(II) and the relative standard deviation for 2.5 mu gL(-1) copper(II) was 3%. The applicability of the method was illustrated by the analysis of soil conditioner samples.
引用
收藏
页码：2920 / 2936
页数：17
相关论文
共 53 条
  • [1] On-site fuel electroanalysis: Determination of lead, copper and mercury in fuel bioethanol by anodic stripping voltammetry using screen-printed gold electrodes
    Almeida, Eduardo S.
    Richter, Eduardo M.
    Munoz, Rodrigo A. A.
    [J]. ANALYTICA CHIMICA ACTA, 2014, 837 : 38 - 43
  • [2] Enhanced electrochemical detection of heavy metals at heated graphite nanoparticle-based screen-printed electrodes
    Aragay, Gemma
    Pons, Josefina
    Merkoci, Arben
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (12) : 4326 - 4331
  • [3] Ashrafi A. M., 2012, SENSING ELECTROANALY, V7, P189
  • [4] Antimony nanoparticle-multiwalled carbon nanotubes composite immobilized at carbon paste electrode for determination of trace heavy metals
    Ashrafi, Amir M.
    Cerovac, Sandra
    Mudric, Sanja
    Guzsvany, Valeria
    Husakova, Lenka
    Urbanova, Iva
    Vytras, Karel
    [J]. SENSORS AND ACTUATORS B-CHEMICAL, 2014, 191 : 320 - 325
  • [5] Ashrafi AM, 2013, INT J ELECTROCHEM SC, V8, P2095
  • [6] New procedures for voltammetric determination of copper (II) using antimony film-coated carbon paste electrodes
    Ashrafi, Amir M.
    Vytras, Karel
    [J]. ELECTROCHIMICA ACTA, 2012, 73 : 112 - 117
  • [7] Ex-situ Antimony Screen-printed Carbon Electrode for Voltammetric Determination of Ni(II)-ions in Wastewater
    Barcelo, Cristian
    Serrano, Nuria
    Arino, Cristina
    Manuel Diaz-Cruz, Jose
    Esteban, Miquel
    [J]. ELECTROANALYSIS, 2016, 28 (03) : 640 - 644
  • [8] Screen-printed electrodes for environmental monitoring of heavy metal ions: a review
    Barton, John
    Gonzalez Garcia, Maria Begona
    Hernandez Santos, David
    Fanjul-Bolado, Pablo
    Ribotti, Alberto
    McCaul, Margaret
    Diamond, Dermot
    Magni, Paolo
    [J]. MICROCHIMICA ACTA, 2016, 183 (02) : 503 - 517
  • [9] Antimony Film Electrode Prepared In Situ in Hydrogen Potassium Tartrate in Anodic Stripping Voltammetric Trace Detection of Cd(II), Pb(II), Zn(II), Tl(I), In(III) and Cu(II)
    Bobrowski, A.
    Putek, M.
    Zarebski, J.
    [J]. ELECTROANALYSIS, 2012, 24 (05) : 1071 - 1078
  • [10] Bobrowski A., 2015, INSIGHTS ANAL ELECTR, V1, P1, DOI DOI 10.21767/2470-9867.100006
123456