Investigation of mechanical properties of transparent conducting oxide thin films

被引:110
作者
Zeng, KY
Zhu, FR
Hu, JQ
Shen, L
Zhang, K
Gong, H
机构
[1] Inst Mat Res & Engn, Singapore 117602, Singapore
[2] Natl Univ Singapore, Dept Mat Sci, Singapore 119260, Singapore
关键词
nano-indentation; elastic properties; hardness; indium tin oxide; indium zinc oxide;
D O I
10.1016/S0040-6090(03)00915-5
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We present an analysis of the mechanical properties of transparent conducting oxide (TCO), indium tin oxide (ITO) and indium zinc oxide (IZO) thin films on the glass substrates. The thin films of ITO and IZO were deposited by radio frequency magnetron sputtering at a low processing temperature. The elastic modulus and hardness of the TCO films prepared at different deposition conditions are determined by nano-indentation experiments. The results show that the presence of hydrogen in a gas mixture during film deposition could vary significantly the hardness and elastic modulus of the ITO films. However, the hardness and elastic modulus of IZO films prepared at the similar conditions are found to be less sensitive to the hydrogen used in the film deposition. The correlation between elastic moduli and the porosity in ceramic materials is used to determine the porosity of the TCO films thus prepared. It is found that the porosity of the ITO films can be changed approximately by 9%, when the films are prepared in the presence of hydrogen in the gas mixture. (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码:60 / 65
页数:6
相关论文
共 25 条
[11]   Nanoindentation characterisation of coated systems:: P:S2 a new approach using the continuous stiffness technique [J].
Page, TF ;
Pharr, GM ;
Hay, JC ;
Oliver, WC ;
Lucas, BN ;
Herbert, E ;
Riester, L .
FUNDAMENTALS OF NANOINDENTATION AND NANOTRIBOLOGY, 1998, 522 :53-64
[12]   HARDNESS MEASUREMENT AT PENETRATION DEPTHS AS SMALL AS 20-NM [J].
PETHICA, JB ;
HUTCHINGS, R ;
OLIVER, WC .
PHILOSOPHICAL MAGAZINE A-PHYSICS OF CONDENSED MATTER STRUCTURE DEFECTS AND MECHANICAL PROPERTIES, 1983, 48 (04) :593-606
[13]   ON THE GENERALITY OF THE RELATIONSHIP AMONG CONTACT STIFFNESS, CONTACT AREA, AND ELASTIC-MODULUS DURING INDENTATION [J].
PHARR, GM ;
OLIVER, WC ;
BROTZEN, FR .
JOURNAL OF MATERIALS RESEARCH, 1992, 7 (03) :613-617
[14]   EFFECTIVE ELASTIC-MODULI OF POROUS CERAMIC MATERIALS [J].
RAMAKRISHNAN, N ;
ARUNACHALAM, VS .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1993, 76 (11) :2745-2752
[15]   EVALUATING POROSITY PARAMETERS FOR POROSITY PROPERTY RELATIONS [J].
RICE, RW .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1993, 76 (07) :1801-1808
[16]  
Wachtman J.B., 1996, Mechanical Properties of Ceramics
[17]   Surface modification of indium tin oxide by plasma treatment: An effective method to improve the efficiency, brightness, and reliability of organic light emitting devices [J].
Wu, CC ;
Wu, CI ;
Sturm, JC ;
Kahn, A .
APPLIED PHYSICS LETTERS, 1997, 70 (11) :1348-1350
[18]   Mechanical and optical properties of ITO films with anti-reflective and anti-wear coatings [J].
Wu, WF ;
Chiou, BS .
APPLIED SURFACE SCIENCE, 1997, 115 (01) :96-102
[19]   Mechanical properties of rf magnetron sputtered indium tin oxide films [J].
Wu, WF ;
Chiou, BS .
THIN SOLID FILMS, 1997, 293 (1-2) :244-250
[20]   Effect of oxygen concentration in the sputtering ambient on the microstructure, electrical and optical properties of radio-frequency magnetron-sputtered indium tin oxide films [J].
Wu, WF ;
Chiou, BS .
SEMICONDUCTOR SCIENCE AND TECHNOLOGY, 1996, 11 (02) :196-202