X-ray crystal structures of copper(II) and cobalt(II) complexes with Schiff base ligands.: Reactivity towards dioxygen

被引：13

作者：

Carré, F

Corriu, RJP

Lancelle-Beltran, E

Mehdi, A

Reyé, C

Guilard, R

Sykora, J

van der Lee, A

机构：

[1] Univ Montpellier 2, Lab Chim Mol & Org Solide, UMR 5637, CNRS, F-34095 Montpellier 5, France

[2] Univ Bourgogne, Lab Ingn Mol Separat & Applicat Gaz, LIMSAG, UMR 5633, F-21100 Dijon, France

[3] Acad Sci Czech Republ, Inst Chem Proc Fundamentals, CR-16502 Prague 6, Czech Republic

[4] Univ Montpellier 2, Inst Europeen Membranes, UMR 5635, CNRS, F-34095 Montpellier 5, France

来源：

DALTON TRANSACTIONS | 2003年 / 16期

关键词：

D O I：

10.1039/b304032a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Copper(II) and cobalt(II) Schiff base complexes with derivatives of the pentadentate ligand bis(salicylideneimino-3-propyl)amine [H(2)salDPT] have been prepared. The X-ray crystal structures of the copper(II) complexes Cu[salDPT] and Cu[sal(n-propyltrimethylsilyl)DPT] were determined and revealed five-coordination at the metal centre in both cases. The 1:1 dioxygen adduct of Co[sal(n-propyltrimethylsilyl)DPT] was also isolated and its X-ray molecular structure determined.

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页码：3211 / 3215

页数：5

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