Compressibility of C-60 in the temperature range 150-335 K up to a pressure of 1 GPa

被引:43
作者
Lundin, A [1 ]
Sundqvist, B [1 ]
机构
[1] UMEA UNIV, DEPT EXPT PHYS, S-90187 UMEA, SWEDEN
关键词
D O I
10.1103/PhysRevB.53.8329
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We have measured the volume of nominally 99.9% pure C-60 as a function of pressure (p) in both the fee and sc phases up to 1 GPa over the temperature range 150 to 335 K using a highly accurate piston-and-cylinder technique. At zero pressure, the room-temperature bulk modulus B(0) is 6.8 GPa for the fee phase acid about 8.7-9.5 GPa for the sc phase. For Be latter phase, B(0) increases strongly with decreasing temperature to 10.4 GPa at 152 K and for both phases B increases rapidly with increasing pressure. The fcc-->sc transformation is always smeared over large ranges inp. Surprisingly, above 200 MPa B is lower in the sc phase than in the fee phase, which we explain as arising from molecular reorientation with increasing pressure. The formation of a mainly ''hexagon''-oriented, ordered phase above 0.6 GPa at low T gives rise to observable anomalies in B(p).
引用
收藏
页码:8329 / 8336
页数:8
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