Graphene-Pd Composite as Highly Active Catalyst for the Suzuki-Miyaura Coupling Reaction

被引：44
作者：
Li, Nan [1 ,2 ]
Wang, Zhiyong [1 ]
Zhao, Keke [1 ]
Shi, Zujin [1 ]
Xu, Shukun [2 ]
Gu, Zhennan [1 ]
机构：
[1] Peking Univ, Beijing Natl Lab Mol Sci, State Key Lab Rare Earth Mat Chem & Applicat, Coll Chem & Mol Engn, Beijing 100871, Peoples R China
[2] Northeastern Univ, Dept Chem, Shenyang 110004, Peoples R China
来源：
JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY | 2010年 / 10卷 / 10期
关键词：
Graphene-Pd Composite; Catalyst; Suzuki-Miyaura Reaction; PALLADIUM NANOPARTICLES; EFFICIENT CATALYST; CARBON; OXIDATION; REDUCTION; SHEETS; HECK;
D O I：
10.1166/jnn.2010.2638
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The graphene-supported Pd catalyst was synthesized using the graphene-Pd salt as precursor. Transmission electron microscope and powder X-ray diffraction analysis indicated the Pd nanoparticles, which supported on the surface of the graphene sheets possessed a face-centered cubic structure and were with the size of 4-8 nm. The Suzuki-Miyaura reaction was employed to analyze the catalytic activity of the graphene-supported Pd catalyst. HPLC analysis indicated that the yield of biphenyl was 97% when the reaction only lasted 10 min. The experimental results showed the graphene sheets were great support for ligand-free Pd catalyst.
引用
收藏
页码：6748 / 6751
页数：4
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