Graphene-Pd Composite as Highly Active Catalyst for the Suzuki-Miyaura Coupling Reaction

被引：44

作者：

Li, Nan ^{[1
,2
]}

Wang, Zhiyong ^{[1
]}

Zhao, Keke ^{[1
]}

Shi, Zujin ^{[1
]}

Xu, Shukun ^{[2
]}

Gu, Zhennan ^{[1
]}

机构：

[1] Peking Univ, Beijing Natl Lab Mol Sci, State Key Lab Rare Earth Mat Chem & Applicat, Coll Chem & Mol Engn, Beijing 100871, Peoples R China

[2] Northeastern Univ, Dept Chem, Shenyang 110004, Peoples R China

来源：

JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY | 2010年 / 10卷 / 10期

关键词：

Graphene-Pd Composite; Catalyst; Suzuki-Miyaura Reaction; PALLADIUM NANOPARTICLES; EFFICIENT CATALYST; CARBON; OXIDATION; REDUCTION; SHEETS; HECK;

D O I：

10.1166/jnn.2010.2638

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The graphene-supported Pd catalyst was synthesized using the graphene-Pd salt as precursor. Transmission electron microscope and powder X-ray diffraction analysis indicated the Pd nanoparticles, which supported on the surface of the graphene sheets possessed a face-centered cubic structure and were with the size of 4-8 nm. The Suzuki-Miyaura reaction was employed to analyze the catalytic activity of the graphene-supported Pd catalyst. HPLC analysis indicated that the yield of biphenyl was 97% when the reaction only lasted 10 min. The experimental results showed the graphene sheets were great support for ligand-free Pd catalyst.

引用

页码：6748 / 6751

页数：4

共 50 条

[1] Pd/DNA as Highly Active and Recyclable Catalyst of Suzuki-Miyaura Coupling
Mart, M.
Tylus, W.
Trzeciak, A. M.
CATALYSTS, 2018, 8 (11):
[2] Highly Dispersed Pd Species Active in the Suzuki-Miyaura Reaction
Okumura, Kazu
Matsui, Hirosuke
Tomiyama, Takuya
Sanada, Takashi
Honma, Tetsuo
Hirayama, Sayaka
Niwa, Miki
CHEMPHYSCHEM, 2009, 10 (18) : 3265 - 3272
[3] Ni/Pd core/shell nanoparticles supported on graphene as a highly active and reusable catalyst for Suzuki-Miyaura cross-coupling reaction
Önder Metin
Sally Fae Ho
Cemalettin Alp
Hasan Can
Max N. Mankin
Mehmet Serdar Gültekin
Miaofang Chi
Shouheng Sun
Nano Research, 2013, 6 : 10 - 18
[4] Ni/Pd core/shell nanoparticles supported on graphene as a highly active and reusable catalyst for Suzuki-Miyaura cross-coupling reaction
Metin, Oender
Ho, Sally Fae
Alp, Cemalettin
Can, Hasan
Mankin, Max N.
Gultekin, Mehmet Serdar
Chi, Miaofang
Sun, Shouheng
NANO RESEARCH, 2013, 6 (01) : 10 - 18
[5] A Highly Active Catalyst System for Suzuki-Miyaura Coupling of Aryl Chlorides
Liu, Guiyan
Han, Fangwai
Liu, Chengxin
Wu, Hongli
Zeng, Yongfei
Zhu, Rongjiao
Yu, Xia
Rao, Shuang
Huang, Genping
Wang, Jianhui
ORGANOMETALLICS, 2019, 38 (07) : 1459 - 1467
[6] Pd nanoparticles immobilized on PNIPAMhalloysite: highly active and reusable catalyst for Suzuki-Miyaura coupling reactions in water
Hong, Myeng Chan
Ahn, Hyunseok
Choi, Myung Chan
Lee, Yongwoo
Kim, Jongsik
Rhee, Hakjune
APPLIED ORGANOMETALLIC CHEMISTRY, 2014, 28 (03) : 156 - 161
[7] Pd@COF-QA: a phase transfer composite catalyst for aqueous Suzuki-Miyaura coupling reaction
Wang, Jian-Cheng
Liu, Cong-Xue
Kan, Xuan
Wu, Xiao-Wei
Kan, Jing-Lan
Dong, Yu-Bin
GREEN CHEMISTRY, 2020, 22 (04) : 1150 - 1155
[8] Phosphine-stabilized Pd nanoparticles supported on silica as a highly active catalyst for the Suzuki-Miyaura cross-coupling reaction
Sahu, Debojeet
Das, Pankaj
RSC ADVANCES, 2015, 5 (05): : 3512 - 3520
[9] Immobilization of Pd on Nanosilica Dendrimer as SILC: Highly Active and Sustainable Cluster Catalyst for Suzuki-Miyaura Reaction
Hagiwara, Hisahiro
Sasaki, Hirokazu
Tsubokawa, Norio
Hoshi, Takashi
Suzuki, Toshio
Tsuda, Tetsuya
Kuwabata, Susumu
SYNLETT, 2010, (13) : 1990 - 1996
[10] Pd-Co bimetallic nanoparticles supported on graphene as a highly active catalyst for Suzuki-Miyaura and Sonogashira cross-coupling reactions
Feng, Yi-Si
Lin, Xin-Yan
Hao, Jian
Xu, Hua-Jian
TETRAHEDRON, 2014, 70 (34) : 5249 - 5253

← 1 2 3 4 5 →