Experimental Critical-Exponent Values for Fluids

被引：161

作者：

Sengers, Jan V. ^{[1
]}

Shanks, Joseph G. ^{[2
]}

机构：

[1] Univ Maryland, Inst Phys Sci & Technol, College Pk, MD 20742 USA

[2] Photon Res Associates Raytheon, San Diego, CA 92121 USA

来源：

JOURNAL OF STATISTICAL PHYSICS | 2009年 / 137卷 / 5-6期

关键词：

Critical correlation function; Critical exponents; Gravity effects; Isobutyric acid plus water; Light scattering; EQUATION-OF-STATE; IONIC BINARY-MIXTURE; TERNARY-SYSTEM; 3-METHYLPYRIDINE/WATER/NABR; UNIVERSAL AMPLITUDE COMBINATIONS; COEXISTENCE-CURVE DIAMETERS; DEUTERATED ISOBUTYRIC ACID; RANGE CORRELATION LENGTH; LIQUID PHASE-TRANSITION; X-RAY-SCATTERING; CRITICAL-BEHAVIOR;

D O I：

10.1007/s10955-009-9840-z

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

After a review of the history and an assessment of the current status of the subject, we present light-scattering data to determine the critical correlation-function exponents for an aqueous electrolyte solution yielding the experimental values gamma=1.238 +/- 0.012, nu=0.629 +/- 0.003, eta=0.032 +/- 0.013. We conclude the paper with some comments concerning the temperature dependence of non-asymptotic effective critical-exponent values of fluids.

引用

页码：857 / 877

页数：21

共 251 条

[61]

CHU B, 1972, BERICH BUNSEN GESELL, V76, P202

[62] CRITICAL EXPONENTS NEAR THE LOWER CONSOLUTE POINT OF NONIONIC MICELLAR SOLUTIONS [J].

CORTI, M ;

DEGIORGIO, V .

PHYSICAL REVIEW LETTERS, 1985, 55 (19) :2005-2008

[63] CRITICAL-BEHAVIOR OF A MICELLAR SOLUTION [J].

CORTI, M ;

DEGIORGIO, V .

PHYSICAL REVIEW LETTERS, 1980, 45 (13) :1045-1048

[64] NON-UNIVERSAL CRITICAL-BEHAVIOR OF MICELLAR SOLUTIONS [J].

CORTI, M ;

DEGIORGIO, V ;

ZULAUF, M .

PHYSICAL REVIEW LETTERS, 1982, 48 (23) :1617-1620

[65] CLOUD POINT TRANSITION IN NONIONIC MICELLAR SOLUTIONS [J].

CORTI, M ;

MINERO, C ;

DEGIORGIO, V .

JOURNAL OF PHYSICAL CHEMISTRY, 1984, 88 (02) :309-317

[66]

DALE HD, 1977, PHYS REV A, V15, P2513

[67] CRITICAL SCATTERING FUNCTION IN A BINARY FLUID MIXTURE - A STUDY OF SODIUM-DEUTEROAMMONIA SOLUTION AT THE CRITICAL CONCENTRATION BY SMALL-ANGLE NEUTRON-SCATTERING [J].

DAMAY, P ;

LECLERCQ, F ;

CHIEUX, P .

PHYSICAL REVIEW B, 1989, 40 (07) :4696-4708

[68] A PRECISE DETERMINATION OF THE CRITICAL INDEX-ETA BY SMALL-ANGLE NEUTRON-SCATTERING (SANS) [J].

DAMAY, P ;

LECLERCQ, F ;

CHIEUX, P .

PHYSICA B, 1989, 156 :223-225

[69] TURBIDITY OF DEUTERATED ISOBUTYRIC ACID AND HEAVY-WATER IN THE ONE-PHASE REGION NEAR THE CRITICAL SOLUTION POINT [J].

DAMORE, LW ;

JACOBS, DT .

JOURNAL OF CHEMICAL PHYSICS, 1992, 97 (01) :464-469

[70] CRITICAL-BEHAVIOR OF HYDROGEN [J].

DEBRUYN, JR ;

BALZARINI, DA .

PHYSICAL REVIEW B, 1989, 39 (13) :9243-9251

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