Synthesis of 2H-pyrroles via iron catalyzed dehydrogenative coupling and C-C bond cleavage

被引：11
作者：
Cui, Suya [1 ]
Wu, Xiaoyun [1 ]
Ma, Wei [1 ]
Tang, Weijun [1 ]
Sun, Huaming [1 ]
Xiao, Jianliang [2 ]
Xue, Dong [1 ]
Wang, Chao [1 ]
机构：
[1] Shaanxi Normal Univ, Sch Chem & Chem Engn, Minist Educ, Key Lab Appl Surface & Colloid Chem, Xian 710119, Peoples R China
[2] Univ Liverpool, Dept Chem, Liverpool L69 7ZD, England
来源：
GREEN SYNTHESIS AND CATALYSIS | 2021年 / 2卷 / 03期
基金：
中国国家自然科学基金;
关键词：
Iron catalysis; Dehydrogenation; Coupling; C -C bond cleavage; N; -heterocycle; ASYMMETRIC HYDROGENATION; ALCOHOLS; IMINES; REARRANGEMENT; TITANOCENE; ACCESS;
D O I：
10.1016/j.gresc.2021.04.007
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Iron catalyzed coupling of fl-amino alcohols with allylic alcohols for the synthesis of 3,4-dihydro-2H-pyrrole derivatives has been developed. Mechanistic studies suggest that the reaction involves iron catalyzed dehydro-genative coupling and C-C bond cleavage processes.
引用
收藏
页码：307 / 310
页数：4
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