C2-Symmetric S/C/S ligands based on N-heterocyclic carbenes: a new ligand architecture for asymmetric catalysis

被引：45

作者：

Iglesias-Siguenza, Javier ^{[1
]}

Ros, Abel ^{[2
]}

Diez, Elena ^{[1
]}

Magriz, Antonio ^{[2
]}

Vazquez, Arcadio ^{[2
]}

Alvarez, Eleuterio ^{[2
]}

Fernandez, Rosario ^{[1
]}

Lassaletta, Jose M. ^{[2
]}

机构：

[1] Univ Seville, Dept Quim Organ, Seville 41071, Spain

[2] CSIC US, Inst Invest Quim, Seville 41092, Spain

来源：

DALTON TRANSACTIONS | 2009年 / 40期

关键词：

STEREOSELECTIVE-SYNTHESIS; CYCLOADDITION REACTIONS; COMPLEXES; YLIDES;

D O I：

10.1039/b910846g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Neutral, C-2-symmetric S/C/S ligands based on N-heterocyclic carbenes and thioether functionalities were incorporated into transition metal complexes characterised by two direct metalstereogenic sulfur bonds. This new ligand design was applied to 1,3-dipolar cycloadditions as the first example of the use silver of carbenes in asymmetric catalysis.

引用

页码：8485 / 8488

页数：4

共 50 条

[31] trans-(2R,3R)-2,3-Diphenylcyclopropane-1,1-dimethanol: a pivotal diol for the synthesis of novel C2-symmetric ligands for asymmetric transition metal catalysis
Vervecken, Elias
Van Overschelde, Michel
Noel, Timothy
Gok, Yasar
Rodriguez, Susana Alvarez
Cogen, Simon
Van der Eycken, Johan
TETRAHEDRON-ASYMMETRY, 2010, 21 (19) : 2321 - 2328
[32] Direct Asymmetric Michael Additions of Ketones to Nitroolefins and Chalcones Catalyzed by a Chiral C2-Symmetric Pyrrolidine-based Tetraamine
Ma Shijun
Wu Lulu
Liu Ming
Wang Yongmei
CHINESE JOURNAL OF CHEMISTRY, 2012, 30 (11) : 2707 - 2713
[33] A novel, C2-symmetric, chiral bis-cyclosulfinamide-olefin tridentate ligand in Rh-catalyzed asymmetric 1,4-additions
Zhang, Li
Tan, Mingchao
Zhou, Lihong
Zeng, Qingle
TETRAHEDRON LETTERS, 2018, 59 (29) : 2778 - 2783
[34] Synthesis of Chiral Aromatic Alcohols: Use of New C2-Symmetric RhIIICp*, RuII(cymene), or RuII(benzene) Complexes Containing Chiral Diaminocyclohexane Ligand as Asymmetric Transfer Hydrogenation Catalyst
Montalvo-Gonzalez, Ruben
Chavez, Daniel
Aguirre, Gerardo
Parra-Hake, Miguel
Somanathan, Ratnasamy
SYNTHETIC COMMUNICATIONS, 2009, 39 (15) : 2737 - 2746
[35] Modular Synthesis of C2-Symmetric Chiral TPy-BPI Pincer Ligands and Application in Asymmetric Ni(II)-Catalysed Friedel-Crafts Alkylation
Cen, Hong-Xing
Ding, Li-Ping
Liu, Lin-Lu
Pan, Wei-Dong
Zhu, Xian-Qiao
Li, Wu-Wu
Zhang, Wen-Jing
Peng, Li-Jun
Liu, Xiong-Li
CHINESE JOURNAL OF CHEMISTRY, 2025, 43 (06) : 599 - 606
[36] A C2-Symmetric Chiral Bis-Sulfoxide Ligand in a Rhodium-Catalyzed Reaction: Asymmetric 1,4-Addition of Sodium Tetraarylborates to Chromenones
Chen, Jun
Chen, Junmin
Lang, Feng
Zhang, Xiangyang
Cun, Linfeng
Zhu, Jin
Deng, Jingen
Liao, Jian
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (13) : 4552 - +
[37] Palladium-Catalyzed Direct C2-Arylation of an N-Heterocyclic Carbene: An Atom-Economic Route to Mesoionic Carbene Ligands
Ghadwal, Rajendra S.
Reichmann, Sven O.
Herbst-Irmer, Regine
CHEMISTRY-A EUROPEAN JOURNAL, 2015, 21 (11) : 4247 - 4251
[38] The role of the aromatic ligand in the asymmetric transfer hydrogenation of the C=N bond on Noyori's chiral Ru catalysts
Sot, Petr
Vilhanova, Beata
Pechacek, Jan
Vaclavik, Jiri
Zapal, Jakub
Kuzma, Marek
Kacer, Petr
TETRAHEDRON-ASYMMETRY, 2014, 25 (18-19) : 1346 - 1351
[39] IPr*Oxa - a new class of sterically-hindered, wingtip-flexible N,C-chelating oxazole-donor N-heterocyclic carbene ligands
Podchorodecka, Pamela
Dziuk, Blazej
Szostak, Roman
Szostak, Michal
Bisz, Elwira
DALTON TRANSACTIONS, 2023, 52 (38) : 13608 - 13617
[40] IBzH (IBenzhydryl): sterically-flexible N-aliphatic N-heterocyclic carbenes (NHCs) for iron-catalyzed C(sp3)-C(sp2) cross-coupling of unactivated haloalkanes
Kardela, Marlena
Dziuk, Blazej
Szostak, Roman
Szostak, Michal
Bisz, Elwira
CATALYSIS SCIENCE & TECHNOLOGY, 2024, 14 (24) : 7002 - 7008

← 1 2 3 4 5 →