C2-Symmetric S/C/S ligands based on N-heterocyclic carbenes: a new ligand architecture for asymmetric catalysis

被引：45

作者：

Iglesias-Siguenza, Javier ^{[1
]}

Ros, Abel ^{[2
]}

Diez, Elena ^{[1
]}

Magriz, Antonio ^{[2
]}

Vazquez, Arcadio ^{[2
]}

Alvarez, Eleuterio ^{[2
]}

Fernandez, Rosario ^{[1
]}

Lassaletta, Jose M. ^{[2
]}

机构：

[1] Univ Seville, Dept Quim Organ, Seville 41071, Spain

[2] CSIC US, Inst Invest Quim, Seville 41092, Spain

来源：

DALTON TRANSACTIONS | 2009年 / 40期

关键词：

STEREOSELECTIVE-SYNTHESIS; CYCLOADDITION REACTIONS; COMPLEXES; YLIDES;

D O I：

10.1039/b910846g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Neutral, C-2-symmetric S/C/S ligands based on N-heterocyclic carbenes and thioether functionalities were incorporated into transition metal complexes characterised by two direct metalstereogenic sulfur bonds. This new ligand design was applied to 1,3-dipolar cycloadditions as the first example of the use silver of carbenes in asymmetric catalysis.

引用

页码：8485 / 8488

页数：4

共 50 条

[21] Synthesis of Chiral C1-Symmetric N-Heterocyclic Carbene Ligands: Application toward Copper-Catalyzed Homocoupling of 2-Naphthols
Holtz-Mulholland, Michael
Collins, Shawn K.
SYNTHESIS-STUTTGART, 2014, 46 (03): : 375 - 380
[22] A New Class of Remote N-Heterocyclic Carbenes with Exceptionally Strong σ-Donor Properties: Introducing Benzo[c]quinolin-6-ylidene
Mayer, Ulrich F. J.
Murphy, Elliot
Haddow, Mairi F.
Green, Michael
Alder, Roger W.
Wass, Duncan F.
CHEMISTRY-A EUROPEAN JOURNAL, 2013, 19 (13) : 4287 - 4299
[23] Design of C2-symmetric salen ligands and their Co(II)- or Yb(III)-complexes, and their role in the reversal of enantioselectivity in the asymmetric Henry reaction
Wu, Shengying
Tang, Jun
Han, Jianwei
Mao, Dan
Liu, Xin
Gao, Xing
Yu, Jianjun
Wang, Limin
TETRAHEDRON, 2014, 70 (35) : 5986 - 5992
[24] Remote steric effects of C2-symmetric planar-chiral terpyridine ligands on copper-catalyzed asymmetric cyclopropanation reactions
Mugishima, Nanako
Kanomata, Nobuhiro
Akutsu, Norihiko
Kubota, Hironobu
TETRAHEDRON LETTERS, 2015, 56 (14) : 1898 - 1903
[25] N-Heterocyclic Carbene-Catalyzed Atom-Economical and Enantioselective Construction of the C-S Bond: Asymmetric Synthesis of Functionalized Thiochromans
Lu, Hong
Zhang, Jia-Lu
Liu, Jin-Yu
Li, Hong -Yu
Xu, Peng-Fei
ACS CATALYSIS, 2017, 7 (11): : 7797 - 7802
[26] Enantioselective Reaction Using Palladium Pincer Complexes with C2-Symmetric Chiral Bis(imidazoline)s
Nakamura, Shuichi
JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 2015, 73 (11) : 8 - 17
[27] C2-Symmetric Chiral Disulfoxide Ligands in Rhodium-Catalyzed 1,4-Addition: From Ligand Synthesis to the Enantioselection Pathway
Mariz, Ronaldo
Poater, Albert
Gatti, Michele
Drinkel, Emma
Buergi, Justus J.
Luan, Xinjun
Blumentritt, Sascha
Linden, Anthony
Cavallo, Luigi
Dorta, Reto
CHEMISTRY-A EUROPEAN JOURNAL, 2010, 16 (48) : 14335 - 14347
[28] N-Heterocyclic Carbenes: Useful Ligands for the Palladium-Catalysed Direct C5 Arylation of Heteroaromatics with Aryl Bromides or Electron-Deficient Aryl Chlorides
Ozdemir, Ismail
Gok, Yetkin
Ozeroglu, Oezlem
Kaloglu, Murat
Doucet, Henri
Bruneau, Christian
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2010, (12) : 1798 - 1805
[29] Saturated N, X-Heterocyclic Carbenes (X = N, O, S, P, Si, C, and B): Stability, Nucleophilicity, and Basicity
Azizi, Zahra
Ghambarian, Mehdi
Rezaei, Mohammad A.
Ghashghaee, Mohammad
AUSTRALIAN JOURNAL OF CHEMISTRY, 2015, 68 (09) : 1438 - 1445
[30] Development of chiral modular bifunctional C2-symmetric bipyridine/phenanthroline-bipyrroloimidazolone ligands and application in noncovalent interaction-assisted enantioselective catalysis
Wang, Xi-Rui
Hu, Pan
Jing, Hui-Xian
Yu, Zhang-Biao
Yao, Zhen
Liu, Xiong-Wei
Zhang, Wen-Jing
Peng, Li-Jun
Liu, Xiong-Li
NEW JOURNAL OF CHEMISTRY, 2025, 49 (04) : 1138 - 1144

← 1 2 3 4 5 →