SYNTHESIS, MOLECULAR STRUCTURE AND SPECTROSCOPIC AND COMPUTATIONAL STUDIES ON 4-(2-(2-(2-FORMYLPHENOXY)ETHOXY)ETHOXY)PHTHALONITRILE AS A FUNCTIONALIZED PHTHALONITRILE

被引：1

作者：

Sen, Pinar ^{[1
]}

Yildiz, Salih Zeki ^{[2
]}

Atalay, Vildan Enisoglu ^{[3
]}

Kanmazalp, Sibel Demir ^{[4
,5
]}

Dege, Necmi ^{[6
]}

机构：

[1] Rhodes Univ, Ctr Nanotechnol Innovat, Dept Chem, POB 94, ZA-6140 Grahamstown, South Africa

[2] Sakarya Univ, Fac Arts & Sci, Dept Chem, TR-54187 Sakarya, Turkey

[3] Uskudar Univ, Fac Engn & Nat Sci, Dept Bioengn, TR-34662 Istanbul, Turkey

[4] Gaziantep Univ, Tech Sci, Gaziantep, Turkey

[5] Gebze Tech Univ, Phys Dept, Kocaeli, Turkey

[6] Ondokuz Mayis Univ, Fac Arts & Sci, Dept Phys, TR-55139 Samsun, Turkey

来源：

MACEDONIAN JOURNAL OF CHEMISTRY AND CHEMICAL ENGINEERING | 2019年 / 38卷 / 01期

关键词：

single crystal; aldehyde; phthalonitrile; DFT; HOMO; LUMO; METAL-COMPLEXES; PM6; METHOD; PHTHALOCYANINES; HARDNESS;

D O I：

10.20450/mjcce.2019.1495

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This work presents the synthesis and characterization of a novel compound, 4-(2-(2-(2-formylphenoxy)ethoxy)ethoxylphthalonitrile as the aldehyde functional group substituted as a phthalonitrile derivative. The spectroscopic properties of the compound were examined through Fourier-transform infrared spectroscopy, Proton nuclear magnetic resonance, Carbon nuclear magnetic resonance, Ultraviolet-visible spectroscopy, Mass spectrometry and elemental analyses. The molecular structure of the compound was also confirmed using X-ray single-crystal data with a theoretical comparative approach.

引用

页码：63 / 74

页数：12

共 29 条

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