The synthesis and characterization of 2,4,6-tris(3,4-dihydroxybenzimino)-1,3,5-triazine and its [salen/salophenFe(III)] and [salen/salophenCr(III)] capped complexes

被引：20

作者：

Uysal, Saban ^{[1
]}

Ucan, H. Ismet ^{[1
]}

机构：

[1] Selcuk Univ, Fac Sci, Dept Chem, TR-42075 Konya, Turkey

来源：

JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY | 2009年 / 65卷 / 3-4期

关键词：

Melamine; Salen; Salophen; Schiff bases; Catechol; SALOPH SCHIFF-BASES; IRON(III) SALEN; EPOXIDATION; BINUCLEAR; CRYSTAL; OLEFINS; CHROMIUM(III); CATALYSIS; NI(II); CU(II);

D O I：

10.1007/s10847-009-9598-6

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Four new trinuclear Fe(III) and Cr(III) complexes involving tetradentate Schiff bases N,N'-bis(salicylidene)ethylenediamine-(salenH(2)) or bis(salicylidene)-o-phenylenediamine-(salophenH(2)) with 2,4,6-tris(3,4-dihydroxybenzimino)-1,3,5-triazine have been synthesized and characterized by means of elemental analysis, H-1 N.M.R., FT-IR spectroscopy, thermal analyses and magnetic susceptibility measurements. The complexes have also been characterized as low-spin distorted octahedral Fe(III) and Cr(III) bridged by catechol group.

引用

页码：403 / 409

页数：7

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