Synthesis of chiral large-ring triangular salen ligands and structural characterization of their complexes

被引：18
|
作者：
Kwit, Marcin [1 ]
Zabicka, Beata [1 ]
Gawronski, Jacek [1 ]
机构：
[1] Adam Mickiewicz Univ, Dept Chem, PL-60780 Poznan, Poland
来源：
DALTON TRANSACTIONS | 2009年 / 34期
关键词：
CRYSTAL-STRUCTURE; TRIANGLIMINE; MACROCYCLES; TRANS-1,2-DIAMINOCYCLOHEXANE; OLIGOIMINES; CATALYST; DIAMINE;
D O I：
10.1039/b909445h
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Large chiral triangular macrocycles having three salen ligand sites were obtained by cyclocondensation of trans-1,2-diaminocyclohexane with linearly connected bis-salicylaldehydes. Structures of the ligands and their titanium(IV) or zinc(II) complexes have been characterized by means of spectroscopic (CD) and computational (DFT) methods.
引用
收藏
页码：6783 / 6789
页数：7
相关论文
共 50 条
  • [21] Salen complexes of zirconium and hafnium: synthesis, structural characterization and polymerization studies
    Mandal, Mrinmay
    Ramkumar, Venkatachalam
    Chakraborty, Debashis
    POLYMER CHEMISTRY, 2019, 10 (25) : 3444 - 3460
  • [22] SYNTHESIS OF LARGE-RING ANALOGS OF ESTRONE BY A RING-EXPANSION ROUTE
    THIES, RW
    PIERCE, JR
    JOURNAL OF ORGANIC CHEMISTRY, 1982, 47 (05): : 798 - 803
  • [23] Effect of ethanol on the synthesis of large-ring cyclodextrins by cyclodextrin glucanotransferases
    Qi, Qingsheng
    Mokhtar, Mohd Noriznan
    Zimmermann, Wolfgang
    JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, 2007, 57 (1-4) : 95 - 99
  • [24] Salen Ligands Revisited: Synthesis and Application of a Planar Chiral "Ferro-Salen" Ligand
    Niemeyer, Jochen
    Kehr, Gerald
    Froehlich, Roland
    Erker, Gerhard
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2010, (05) : 680 - 684
  • [25] Synthesis, Characterization, Biological and Thermal Studies of Cu(II) Complexes of Salen and Tetrahedrosalen Ligands
    Khanmohammadi, H.
    Salehifard, M.
    Abnosi, M. H.
    JOURNAL OF THE IRANIAN CHEMICAL SOCIETY, 2009, 6 (02) : 300 - 309
  • [26] New Strategies for Medium- and Large-Ring Lactone Synthesis
    Zhao, Wanxiang
    Sun, Jianwei
    SYNLETT, 2014, 25 (03) : 303 - 307
  • [27] Synthesis and structural characterization of isomeric palladium(II) complexes with chiral N,O-bidentate ligands
    Tsuno, Takashi
    Iwabe, Haruka
    Brunner, Henri
    INORGANICA CHIMICA ACTA, 2013, 400 : 262 - 266
  • [28] Synthesis, structural characterization, and properties of three Ag(I) complexes with oxazoline-containing chiral ligands
    Kuai, Hai-Wei
    Cheng, Xiao-Chun
    Zhu, Xiao-Hong
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2021, 76 (05): : 327 - 331
  • [29] Synthesis and Characterization of Some Chiral Metal-Salen Complexes Bearing a Ferrocenophane Substituent
    Patti, Angela
    Pedotti, Sonia
    Ballistreri, Francesco Paolo
    Sfrazzetto, Giuseppe Trusso
    MOLECULES, 2009, 14 (11): : 4312 - 4325
  • [30] Synthesis of novel chiral 'salen-type' ferrocenyl ligands
    Ballistreri, Francesco P.
    Patti, Angela
    Pedotti, Sonia
    Tomaselli, Gaetano A.
    Toscano, Rosa M.
    TETRAHEDRON-ASYMMETRY, 2007, 18 (20) : 2377 - 2380
12345