catena-Poly[calcium-bis[μ-N-(dimethylphosphinoyl)benzenesulfonamidato]]

被引：2
作者：
Trush, Elizaveta A. [1 ]
Trush, Victor A. [1 ]
Sliva, Tetyana Yu. [1 ]
Konovalova, Irina S. [2 ]
Amirkhanov, Volodymyr M. [1 ]
机构：
[1] Natl Taras Shevchenko Univ, Dept Chem, UA-01033 Kiev, Ukraine
[2] STC Inst Single Crystals, UA-61001 Kharkov, Ukraine
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷
关键词：
CHEMICAL VAPOR-DEPOSITION; FILMS;
D O I：
10.1107/S1600536809032875
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The crystal structure of the title calcium complex, [Ca(C(8)H(11-)NO(5)PS)(2)](n), is composed of a polymeric chain, which is formed due to two bridging sulfonyl groups linking Ca(II) ions in a O-S-O-Ca manner. Thus, the coordination environment of the Ca(II) ions is composed of six O atoms belonging to the phosphoryl and sulfonyl groups of two chelate rings and two additional O atoms of two bridging sulfonyl groups. The coordination polyhedron of the central atom (2 symmetry) has a distorted octahedral geometry.
引用
收藏
页码：M1231 / +
页数：9
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