Surface-initiated ring-opening metathesis polymerization on Si/SiO2

被引：156

作者：

Kim, NY

Jeon, NL

Choi, IS

Takami, S

Harada, Y

Finnie, KR

Girolami, GS

Nuzzo, RG

Whitesides, GM

Laibinis, PE

机构：

[1] Univ Illinois, Dept Chem, Urbana, IL 61801 USA

[2] Univ Illinois, Seitz Mat Res Lab, Urbana, IL 61801 USA

[3] MIT, Dept Chem, Cambridge, MA 02139 USA

[4] Harvard Univ, Dept Chem & Chem Biol, Cambridge, MA 02138 USA

[5] MIT, Dept Chem Engn, Cambridge, MA 02139 USA

来源：

MACROMOLECULES | 2000年 / 33卷 / 08期

关键词：

D O I：

10.1021/ma000046c

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A method for growing thin polymer films from the surface of a silicon wafer bearing a native oxide (Si/SiO2) by ring-opening metathesis polymerization (ROMP) is described. The norbornene-derived polymer films were prepared with a wide range of thicknesses up to 1 μm and with a control over the chemical composition of the film perpendicular to the surface. It was observed that surface-initiated polymerization using ROMP can be used to grow covalently attached norbornene-based polymer films from an oxide surface by solution phase procedures.

引用

收藏

页码：2793 / 2795

页数：3

相关论文

共 18 条

[1] Surface-initiated radical polymerization on porous silica [J].

Huang, XY ;

Wirth, MJ .

ANALYTICAL CHEMISTRY, 1997, 69 (22) :4577-4580

[2]

Husemann M, 1999, ANGEW CHEM INT EDIT, V38, P647, DOI 10.1002/(SICI)1521-3773(19990301)38:5<647::AID-ANIE647>3.0.CO

[3]

2-0

[4] Controlled synthesis of polymer brushes by "Living" free radical polymerization techniques [J].

Husseman, M ;

Malmström, EE ;

McNamara, M ;

Mate, M ;

Mecerreyes, D ;

Benoit, DG ;

Hedrick, JL ;

Mansky, P ;

Huang, E ;

Russell, TP ;

Hawker, CJ .

MACROMOLECULES, 1999, 32 (05) :1424-1431

[5] Patterned polymer growth on silicon surfaces using microcontact printing and surface-initiated polymerization [J].

Jeon, NL ;

Choi, IS ;

Whitesides, GM ;

Kim, NY ;

Laibinis, PE ;

Harada, Y ;

Finnie, KR ;

Girolami, GS ;

Nuzzo, RG .

APPLIED PHYSICS LETTERS, 1999, 75 (26) :4201-4203

[6] Surface-initiated anionic polymerization of styrene by means of self-assembled monolayers [J].

Jordan, R ;

Ulman, A ;

Kang, JF ;

Rafailovich, MH ;

Sokolov, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (05) :1016-1022

[7] Surface initiated living cationic polymerization of 2-oxazolines [J].

Jordan, R ;

Ulman, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (02) :243-247

[8]

KENNEDY JP, 1967, J MACROMOL SCI CHEM, V3, P345

[9] Micron-scale patterning of hyperbranched polymer films by micro-contact printing [J].

Lackowski, WM ;

Ghosh, P ;

Crooks, RM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (06) :1419-1420

[10] RING-OPENING METATHESIS POLYMERIZATION OF SUBSTITUTED NORBORNENES [J].

MAKOVETSKY, KL ;

FINKELSHTEIN, ES ;

OSTROVSKAYA, IY ;

PORTNYKH, EB ;

GORBACHEVA, LI ;

GOLDBERG, AL ;

USHAKOV, NV ;

YAMPOLSKY, YP .

JOURNAL OF MOLECULAR CATALYSIS, 1992, 76 (1-3) :107-121