Surface-initiated ring-opening metathesis polymerization on Si/SiO2

被引：155
|
作者：
Kim, NY
Jeon, NL
Choi, IS
Takami, S
Harada, Y
Finnie, KR
Girolami, GS
Nuzzo, RG
Whitesides, GM
Laibinis, PE
机构：
[1] Univ Illinois, Dept Chem, Urbana, IL 61801 USA
[2] Univ Illinois, Seitz Mat Res Lab, Urbana, IL 61801 USA
[3] MIT, Dept Chem, Cambridge, MA 02139 USA
[4] Harvard Univ, Dept Chem & Chem Biol, Cambridge, MA 02138 USA
[5] MIT, Dept Chem Engn, Cambridge, MA 02139 USA
来源：
MACROMOLECULES | 2000年 / 33卷 / 08期
关键词：
D O I：
10.1021/ma000046c
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A method for growing thin polymer films from the surface of a silicon wafer bearing a native oxide (Si/SiO2) by ring-opening metathesis polymerization (ROMP) is described. The norbornene-derived polymer films were prepared with a wide range of thicknesses up to 1 μm and with a control over the chemical composition of the film perpendicular to the surface. It was observed that surface-initiated polymerization using ROMP can be used to grow covalently attached norbornene-based polymer films from an oxide surface by solution phase procedures.
引用
收藏
页码：2793 / 2795
页数：3
相关论文
共 50 条
  • [1] Surface-initiated ring-opening metathesis polymerization from cellulose fibers
    Carlmark, Anna E.
    Carlsson, Linn
    Malmstrom, Eva E.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2011, 242
  • [2] An efficient approach to surface-initiated ring-opening metathesis polymerization of cyclooctadiene
    Feng, Jianxin
    Stoddart, Stephanie S.
    Weerakoon, Kanchana A.
    Chen, Wei
    LANGMUIR, 2007, 23 (03) : 1004 - 1006
  • [3] Surface-Initiated Ring-Opening Metathesis Polymerization of Dicyclopentadiene from the Vapor Phase
    Njoroge, Ian
    Kempler, Paul A.
    Deng, Xuanli
    Arnold, Steven T.
    Jennings, G. Kane
    LANGMUIR, 2017, 33 (49) : 13903 - 13912
  • [4] Preparation of films formed by surface-initiated ring-opening metathesis polymerization.
    Kim, NY
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2000, 219 : U560 - U560
  • [5] Surface-initiated ring-opening metathesis polymerization (SiROMP) of cyclooctadiene (COD) and subsequent hydroxylation
    Hang, Mimi N.
    Lerum, Maria F. Z.
    Chen, Wei
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2010, 240
  • [6] Covalent modification of graphene oxide with polynorbornene by surface-initiated ring-opening metathesis polymerization
    Zhang, Qiuping
    Li, Qing-Lan
    Xiang, Shidong
    Wang, Yan
    Wang, Chunyang
    Jiang, Wei
    Zhou, Hang
    Yang, Ying-Wei
    Tang, Jun
    POLYMER, 2014, 55 (23) : 6044 - 6050
  • [7] Surface grafting of electrochemically crosslinked PEDOT brushes via surface-initiated ring-opening metathesis polymerization
    Yavuz, Mustafa Selman
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 247
  • [8] Synthesis of Polyolefin/Layered Silicate Nanocomposites via Surface-Initiated Ring-Opening Metathesis Polymerization
    Kalluru, Sri Harsha
    Cochran, Eric W.
    MACROMOLECULES, 2013, 46 (23) : 9324 - 9332
  • [9] Surface-initiated ring-opening metathesis polymerisation from cellulose fibres
    Carlsson, Linn
    Malmstrom, Eva
    Carlmark, Anna
    POLYMER CHEMISTRY, 2012, 3 (03) : 727 - 733
  • [10] Surface-Initiated Ring-Opening Metathesis Polymerization (SI-ROMP): History, General Features, and Applications in Surface Engineering with Polymer Brushes
    Chen, Qingchuan
    INTERNATIONAL JOURNAL OF POLYMER SCIENCE, 2021, 2021
12345