Syntheses, structures and magnetic properties of a series of lanthanide complexes based on p-methoxybenzoic acid

被引：5

作者：

Du, Yan-Zhu ^{[1
]}

Zheng, Ji-Min ^{[1
]}

机构：

[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2016年 / 66卷

基金：

中国国家自然科学基金;

关键词：

Crystal structures; Lanthanide complexes; Solvothermal synthesis; Magnetic properties; ORGANIC FRAMEWORKS; COORDINATION; PHOTOLUMINESCENCE; TOPOLOGY; CRYSTAL; CLUSTER;

D O I：

10.1016/j.inoche.2016.01.020

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new series of lanthanide metal complexes [Ln(L)(3)](n) (L = p-methoxybenzoic acid, Ln = Pr 1, Eu 2, Tb 3, Dy 4, Ho 5, Er 6, Yb 7) have been synthesized under hydrothermal conditions. Single-crystal X-ray diffraction measurements reveal that these compounds are isostructural, crystallizing in the monoclinic space group P2(1)/c and giving 1D chain structures. Magnetic studies reveal antiferromagnetic behavior for complexes 1, 3, 5 and 6, ferromagnetic behavior for complex 4 and spin-canting behavior for 7. (C) 2016 Elsevier B.V. All rights reserved.

引用

页码：59 / 63

页数：5

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