Inner-outer ring 1,3-bis(trimethylsilyloxy)-1,3-dienes as useful intermediates in the synthesis of helicenes

被引：0
作者：
Real, MD [1 ]
Sestelo, JP [1 ]
Sarandeses, LA [1 ]
机构：
[1] Univ A Coruna, Dept Quim Fundamental, E-15071 La Coruna, Spain
来源：
TETRAHEDRON LETTERS | 2002年 / 43卷 / 50期
关键词：
3-bis(trimethylsilyloxy)-1,3-dienes; Diels-Alder reactions; helicenes; quinones; sulfoxides;
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Functionalized benzo[c]phenanthrenes ([4]helicenes) and [5]helicenes were synthesised in five steps from tetra-hydronaphthalenone and tetrahydrophenanthrenone compounds using a novel synthetic approach based on a Diels-Alder reaction between inner-outer ring 1,3-bis(trimetliylsilyloxy)-1,3-dienes and benzyne or quinones. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：9111 / 9114
页数：4
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