NaBaLa2(PO4)3: A novel host lattice for Sm3+-doped phosphor materials emitting reddish-orange light

被引：96
|
作者：
Li, Li [1 ,2 ]
Tang, Xiaohua [3 ]
Jiang, Zhouqing [4 ,5 ]
Zhou, Xianju [1 ]
Jiang, Sha [1 ]
Luo, Xiaobing [1 ]
Xiang, Guotao [1 ]
Zhou, Kaining [1 ]
机构：
[1] Chongqing Univ Posts and Telecommun, Coll Sci, Chongqing 400065, Peoples R China
[2] Polish Acad Sci, Inst Phys, Al Lotnikow 32-46, PL-02668 Warsaw, Poland
[3] Chongqing Univ Posts & Telecommun, Coll Optoelect Engn, Chongqing 400065, Peoples R China
[4] Gen Res Inst Nonferrous Met, Natl Engn Res Ctr Rare Earth Mat, Beijing 100088, Peoples R China
[5] Grirem Adv Mat Co Ltd, Beijing 100088, Peoples R China
来源：
JOURNAL OF ALLOYS AND COMPOUNDS | 2017年 / 701卷
基金：
中国国家自然科学基金;
关键词：
NaBaLa2(PO4)(3):Sm3+; Reddish-orange phosphor; Luminescence; ENERGY-TRANSFER PROPERTIES; PHOTOLUMINESCENCE PROPERTIES; LUMINESCENCE PROPERTIES; TUNABLE EMISSION; SM3+; UV; COLOR; CE3+; APATITE; TB3+;
D O I：
10.1016/j.jallcom.2017.01.171
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A series of reddish orange light-emitting NaBaLa2(PO4)(3): Sm3+(NBLP:Sm3+) phosphors are designed and synthesized in this work for the first time. The crystal structure of NaBaLa2(PO4)(3): Sm3+(NBLP) has been studied by the Rietveld refinement analysis, which shows that the NBLP belongs to eulytite-type orthophosphate. Luminescence properties of NBLP:Sm3+ phosphors were investigated in detail, including excitation and emission spectra, concentration quenching, fluorescence decay, Inokuti-Hirayama (I-H) model analysis, etc. The Commission Internationale de L'Eclairage (CIE) coordinates exhibited a shift slightly from reddish-orange (0.5782, 0.4171) to orange (0.5605, 0.4312) with the increase of Sm3+ concentration. In addition, the NBLP:Sm3+ phosphor shows good thermal stability and acceptable quantum efficiency. From the obtained results, the prepared phosphor NBLP: Sm3+ can be demonstrated as a potential orange-red luminescent material. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码：515 / 523
页数：9
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