Dielectric measurement study of lamellar CuInP2Se6:: successive transitions towards a ferroelectric state via an incommensurate phase?

被引:37
作者
Vysochanskii, YM
Molnar, AA
Gurzan, MI
Cajipe, VB
Bourdon, X
机构
[1] Uzhgorod State Univ, Inst Solid State Phys & Chem, UA-294000 Uzhgorod, Ukraine
[2] Inst Mat Jean Rouxel, F-44322 Nantes 3, France
关键词
ferroelectrics; dielectric response; phase transitions;
D O I
10.1016/S0038-1098(00)00131-9
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
The dielectric properties of lamellar CuInP2Se6 are studied as a function of temperature. Two phase transitions are detected: a second-order one at T-i = 248 K and a first-order transition at T-c = 236 K. These observations confirm the assumed paraelectric and ferroelectric character of the high- and low-temperature phases and give the first indication of an intermediate dipole state existing in this material. The hypothesis of an incommensurate phase occurring between T-i and T-c and the possible appearance of a Lifshitz point in CuInP2(SexS1-x)(6) are discussed. (C) 2000 Published by Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:13 / 17
页数:5
相关论文
共 22 条
[11]   Multicritical behavior in ferroelectrics [J].
Folk, R .
PHASE TRANSITIONS, 1999, 67 (04) :645-666
[12]   LIFSHITZ POINTS IN UNIAXIAL FERROELECTRICS [J].
FOLK, R ;
MOSER, G .
PHYSICAL REVIEW B, 1993, 47 (21) :13992-13997
[13]   SYMMETRY-DERIVED CRITICAL MODES AT THE FERROMAGNETIC LIFSHITZ POINT [J].
HORNREICH, RM ;
LUBAN, M ;
SHTRIKMAN, S .
PHYSICAL REVIEW B, 1979, 19 (07) :3799-3807
[14]  
ISHIBASHI Y, 1978, J PHYS SOC JPN, V45, P408
[15]   Ferrielectric ordering in lamellar CuInP2S6 [J].
Maisonneuve, V ;
Cajipe, VB ;
Simon, A ;
VonDerMuhll, R ;
Ravez, J .
PHYSICAL REVIEW B, 1997, 56 (17) :10860-10868
[16]   LOW-TEMPERATURE NEUTRON POWDER DIFFRACTION STUDY OF CUCRP2S6 - OBSERVATION OF AN ORDERED, ANTIPOLAR COPPER SUBLATTICE [J].
MAISONNEUVE, V ;
CAJIPE, VB ;
PAYEN, C .
CHEMISTRY OF MATERIALS, 1993, 5 (06) :758-760
[17]   PHASE-DIAGRAMS NEAR LIFSHITZ POINT .1. UNIAXIAL MAGNETIZATION [J].
MICHELSON, A .
PHYSICAL REVIEW B, 1977, 16 (01) :577-584
[18]   PHASE-DIAGRAMS NEAR LIFSHIFTZ POINT .2. SYSTEMS WITH CYLINDRICAL, HEXAGONAL, AND RHOMBOHEDRAL SYMMETRY HAVING AN EASY PLANE OF MAGNETIZATION [J].
MICHELSON, A .
PHYSICAL REVIEW B, 1977, 16 (01) :585-592
[19]  
MOLNAR AA, 1994, SOV PHYS JETP, V79, P1994
[20]   PARAELECTRIC FERROELECTRIC TRANSITION IN THE LAMELLAR THIOPHOSPHATE CUINP2S6 [J].
SIMON, A ;
RAVEZ, J ;
MAISONNEUVE, V ;
PAYEN, C ;
CAJIPE, VB .
CHEMISTRY OF MATERIALS, 1994, 6 (09) :1575-1580