Formation and Dynamics of Ion-Stabilized Gas Nanobubble Phase in the Bulk of Aqueous NaCL Solutions

被引：81

作者：

Bunkin, Nikolai F. ^{[1
,2
]}

Shkirin, Alexey V. ^{[2
,3
]}

Suyazov, Nikolay V. ^{[2
]}

Babenko, Vladimir A. ^{[4
]}

Sychev, Andrey A. ^{[1
,4
]}

Penkov, Nikita V. ^{[5
]}

Belosludtsev, Konstantin N. ^{[6
]}

Gudkov, Sergey V. ^{[2
,6
,7
]}

机构：

[1] Bauman Moscow State Tech Univ, Second Baumanskaya 5, Moscow 105005, Russia

[2] Russian Acad Sci, AM Prokhorov Gen Phys Inst, Ul Vavilova 38, Moscow 119991, Russia

[3] Natl Res Nucl Univ MEPhI, Kashirskoe Sh 31, Moscow 115409, Russia

[4] Russian Acad Sci, PN Lebedev Phys Inst, Leninskiy Prospekt 53, Moscow 119991, Russia

[5] Russian Acad Sci, Inst Cell Biophys, Inst Skaya Ul 3, Pushchino 142290, Moscow Region, Russia

[6] Russian Acad Sci, Inst Theoret & Expt Biophys, Inst Skaya Ul 3, Pushchino 142290, Moscow Region, Russia

[7] Lobachevsky State Univ Nizhni Novgorod, Pr Gagarina 23, Nizhnii Novgorod 603950, Russia

来源：

JOURNAL OF PHYSICAL CHEMISTRY B | 2016年 / 120卷 / 07期

关键词：

OPTICAL-BREAKDOWN; DISSOLVED-GAS; HYDROPHOBIC ATTRACTION; HYDROGEN NANOBUBBLES; SALT-SOLUTIONS; WATER; SURFACE; ELECTROLYTES; SCATTERING; INTERFACE;

D O I：

10.1021/acs.jpcb.5b11103

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Ion-stabilized gas nanobubbles (the so-termed "bubstons") and their clusters are investigated in bulk aqueous solutions of NaCl at different ion concentrations by four independent laser diagnostic methods. It turned out that in the range of NaCl concentration 10(-6) < C < 1 M the radius of bubston remains virtually unchanged at a value of 100 nm. Bubstons and their clusters are a thermodynamically non-equilibrium phase, which has been demonstrated in experiments with magnetic stirrer at different stirring rates. Different regimes of the bubston generation, resulting from various techniques of processing the liquid samples, were explored.

引用

页码：1291 / 1303

页数：13

共 50 条

[31] Generation of AgCl Cubes by Excimer Laser Ablation of Bulk Ag in Aqueous NaCl Solutions
Yan, Zijie
Compagnini, Giuseppe
Chrisey, Douglas B.
JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (12): : 5058 - 5062
[32] Identification of Ion Pairs in Aqueous NaCl and KCl Solutions in Combination with Raman Spectroscopy, Molecular Dynamics, and Quantum Chemical Calculations
Wang, Lin
Morita, Akihiro
North, Nicole M.
Baumler, Stephen M.
Springfield, Elliot W.
Allen, Heather C.
JOURNAL OF PHYSICAL CHEMISTRY B, 2023, 127 (07): : 1618 - 1627
[33] Laser diagnostics of the Bubston phase in the bulk of aqueous salt solutions
Bunkin, N. F.
Shkirin, A. V.
Babenko, V. A.
Sychev, A. A.
Lomkova, A. K.
Kulikov, E. S.
PHYSICS OF WAVE PHENOMENA, 2015, 23 (03) : 161 - 175
[34] Laser diagnostics of the Bubston phase in the bulk of aqueous salt solutions
N. F. Bunkin
A. V. Shkirin
V. A. Babenko
A. A. Sychev
A. K. Lomkova
E. S. Kulikov
Physics of Wave Phenomena, 2015, 23 : 161 - 175
[35] ION AND SOLVENT DYNAMICS IN AQUEOUS TETRAMETHYLAMMONIUM CHLORIDE SOLUTIONS
BROWN, AN
NEWBERY, M
THOMAS, RK
WHITE, JW
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS II, 1988, 84 : 17 - 33
[36] Role of Mutual Diffusion in the Dissolution Behavior of One Primary Bulk Gas Nanobubble in Liquid: A Molecular Dynamics Study
Li, Yuhan
Zhang, Lu-Wen
Wang, Benlong
LANGMUIR, 2023, 39 (22) : 7684 - 7693
[37] FORMATION OF BISULFATE-ION IN AQUEOUS-SOLUTIONS
FEDOROV, VA
KALOSH, TN
DERYAGINA, NR
ZHURNAL NEORGANICHESKOI KHIMII, 1979, 24 (09): : 2317 - 2321
[38] Ion-solvent and ion-ion interactions of NaCl aqueous and aqueous maltose solutions at 298–323 K on viscosity data
Summyia Masood
Rehana Saeed
Maria Ashfaq
Afshan Irfan
Russian Journal of Physical Chemistry A, 2014, 88 : 2102 - 2107
[39] Structure of NaCl and KCl concentrated aqueous solutions by ab initio molecular dynamics
Cavallari, M
Cavazzoni, C
Ferrario, M
MOLECULAR PHYSICS, 2004, 102 (9-10) : 959 - 966
[40] Phase equilibrium conditions for simulated landfill gas hydrate formation in aqueous solutions of tetrabutylammonium nitrate
Shi, Ling-Li
Liang, De-Qing
Li, Dong-Liang
JOURNAL OF CHEMICAL THERMODYNAMICS, 2014, 68 : 322 - 326

← 1 2 3 4 5 →