Formation and Dynamics of Ion-Stabilized Gas Nanobubble Phase in the Bulk of Aqueous NaCL Solutions

被引：81

作者：

Bunkin, Nikolai F. ^{[1
,2
]}

Shkirin, Alexey V. ^{[2
,3
]}

Suyazov, Nikolay V. ^{[2
]}

Babenko, Vladimir A. ^{[4
]}

Sychev, Andrey A. ^{[1
,4
]}

Penkov, Nikita V. ^{[5
]}

Belosludtsev, Konstantin N. ^{[6
]}

Gudkov, Sergey V. ^{[2
,6
,7
]}

机构：

[1] Bauman Moscow State Tech Univ, Second Baumanskaya 5, Moscow 105005, Russia

[2] Russian Acad Sci, AM Prokhorov Gen Phys Inst, Ul Vavilova 38, Moscow 119991, Russia

[3] Natl Res Nucl Univ MEPhI, Kashirskoe Sh 31, Moscow 115409, Russia

[4] Russian Acad Sci, PN Lebedev Phys Inst, Leninskiy Prospekt 53, Moscow 119991, Russia

[5] Russian Acad Sci, Inst Cell Biophys, Inst Skaya Ul 3, Pushchino 142290, Moscow Region, Russia

[6] Russian Acad Sci, Inst Theoret & Expt Biophys, Inst Skaya Ul 3, Pushchino 142290, Moscow Region, Russia

[7] Lobachevsky State Univ Nizhni Novgorod, Pr Gagarina 23, Nizhnii Novgorod 603950, Russia

来源：

JOURNAL OF PHYSICAL CHEMISTRY B | 2016年 / 120卷 / 07期

关键词：

OPTICAL-BREAKDOWN; DISSOLVED-GAS; HYDROPHOBIC ATTRACTION; HYDROGEN NANOBUBBLES; SALT-SOLUTIONS; WATER; SURFACE; ELECTROLYTES; SCATTERING; INTERFACE;

D O I：

10.1021/acs.jpcb.5b11103

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Ion-stabilized gas nanobubbles (the so-termed "bubstons") and their clusters are investigated in bulk aqueous solutions of NaCl at different ion concentrations by four independent laser diagnostic methods. It turned out that in the range of NaCl concentration 10(-6) < C < 1 M the radius of bubston remains virtually unchanged at a value of 100 nm. Bubstons and their clusters are a thermodynamically non-equilibrium phase, which has been demonstrated in experiments with magnetic stirrer at different stirring rates. Different regimes of the bubston generation, resulting from various techniques of processing the liquid samples, were explored.

引用

页码：1291 / 1303

页数：13

共 50 条

[1] Ion-Specific and Thermal Effects in the Stabilization of the Gas Nanobubble Phase in Bulk Aqueous Electrolyte Solutions
Yurchenko, Stanislav O.
Shkirin, Alexey V.
Ninham, Barry W.
Sychev, Andrey A.
Babenko, Vladimir A.
Penkov, Nikita V.
Kryuchkov, Nikita P.
Bunkin, Nikolai F.
LANGMUIR, 2016, 32 (43) : 11245 - 11255
[2] Study of the nanobubble phase of aqueous NaCl solutions by dynamic light scattering
Bunkin, N. F.
Shkirin, A. V.
Burkhanov, I. S.
Chaikov, L. L.
Lomkova, A. K.
QUANTUM ELECTRONICS, 2014, 44 (11) : 1022 - 1028
[3] Cobalt Ion-Stabilized VO2 for Aqueous Ammonium Ion Hybrid Supercapacitors
Chen, Qiang
Tang, Zheyu
Li, Hang
Liang, Wenlong
Zeng, Yuquan
Zhang, Jianli
Hou, Guangya
Tang, Yiping
ACS APPLIED MATERIALS & INTERFACES, 2024, 16 (15) : 18824 - 18832
[4] Ion-stabilized block copolymer micelles: Film formation and intermicellar interaction
Spatz, JP
Sheiko, S
Moller, M
MACROMOLECULES, 1996, 29 (09) : 3220 - 3226
[5] Nanobubble Dynamics in Aqueous Surfactant Solutions Studied by Liquid-Phase Transmission Electron Microscopy
Bae, Yuna
Kang, Sungsu
Kim, Byung Hyo
Lim, Kitaek
Jeon, Sungho
Shim, Sangdeok
Lee, Won Chul
Park, Jungwon
ENGINEERING, 2021, 7 (05) : 630 - 635
[6] Ion-Ion Structural Correlation and Dynamics of Water in Aqueous NaCl Solutions with a Wide Range of Concentrations
Khushika, Pritam Kumar
Jana, Pritam Kumar
JOURNAL OF PHYSICAL CHEMISTRY B, 2025, 129 (05): : 1675 - 1688
[7] Molecular dynamics simulation of gas phase ion cluster formation
Cabarcos, OM
Lisy, JM
INTERNATIONAL JOURNAL OF MASS SPECTROMETRY, 1999, 185 : 883 - 903
[8] Formation of gas hydrates from single-phase aqueous solutions
Holder, GD
Mokka, LP
Warzinski, RP
CHEMICAL ENGINEERING SCIENCE, 2001, 56 (24) : 6897 - 6903
[9] Phase Equilibria of Natural Gas Hydrates in the Presence of Methanol, Ethylene Glycol, and NaCl Aqueous Solutions
Lee, Jong-Won
Kang, Seong-Pil
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2011, 50 (14) : 8750 - 8755
[10] Molecular Dynamics Study of Aqueous NaCl Solutions: Flash Crystallization Caused by Solution Phase Change
Kobayashi, Kazuya
Liang, Yunfeng
Matsuoka, Toshifumi
JOURNAL OF SOLUTION CHEMISTRY, 2014, 43 (9-10) : 1799 - 1809

← 1 2 3 4 5 →