Selective Synthesis of [12]Cycloparaphenylene

被引：403

作者：

Takaba, Hiroko ^{[1
]}

Omachi, Haruka ^{[1
]}

Yamamoto, Yosuke ^{[1
]}

Bouffard, Jean ^{[1
]}

Itami, Kenichiro ^{[1
]}

机构：

[1] Nagoya Univ, Grad Sch Sci, Dept Chem, Chikusa Ku, Nagoya, Aichi 4648602, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 33期

关键词：

aromaticity; cross-coupling; cycloparaphenylenes; macrocyclization; palladium; NONPLANAR AROMATIC-COMPOUNDS; CROSS-COUPLING REACTIONS; TUBE-SHAPED MOLECULES; DOUBLE-STRANDED CYCLE; H BOND ARYLATION; BELT REGION; ORGANOBORON COMPOUNDS; ARYLBORONIC ACIDS; CARBON SKELETON; PI-SYSTEMS;

D O I：

10.1002/anie.200902617

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Tighten your belt: [12]Cycloparaphenylene, the sidewall segment of a carbon nanotube (see picture), has been synthesized in a selective manner through stepwise palladium-catalyzed coupling reactions. The synthesis capitalizes on the ability of the cis-1,4-dihydroxycyclohexane- 1,4-diyl unit to attenuate the build-up of strain energy during macrocyclization. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：6112 / 6116

页数：5