Formation of Y-junction carbon nanotubes by catalytic CVD of methane

被引:16
作者
Chai, Siang-Piao [1 ]
Zein, Sharif Hussein Sharif [1 ]
Mohamed, Abdul Rahman [1 ]
机构
[1] Univ Sains Malaysia, Sch Chem Engn, Nibong Tebal 14300, Malaysia
关键词
Y-junction carbon nanotubes; supported metal catalysts; chemical vapor deposition; transmission electron microscopy;
D O I
10.1016/j.ssc.2006.08.006
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
Y-junction carbon nanotubes were grown by catalytic CVD of methane at 700 degrees C on NiO-CuO-MoO(7:2:1)(w/w/w)/SiO2 catalyst. For comparison, NiO-CuO(8:2)(w/w)/SiO2 and NiO-MoO(8:2)(w/w)/SiO2 catalysts were tested for carbon nanotube formation. TEM analysis indicates that no Y-junction structures were formed with the latter two catalysts. This finding elucidates why the addition of a small amount of Moo to NiO-CuO/SiO2 catalyst is crucial for enhancing the formation of Y-junction carbon nanotubes. (c) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码:248 / 250
页数:3
相关论文
共 11 条
[1]   Carbon nanotubes - the route toward applications [J].
Baughman, RH ;
Zakhidov, AA ;
de Heer, WA .
SCIENCE, 2002, 297 (5582) :787-792
[2]   Carbon nanotube Y junctions:: growth and properties [J].
Biró, LP ;
Horváth, ZE ;
Márk, GI ;
Osváth, Z ;
Koós, AA ;
Benito, AM ;
Maser, W ;
Lambin, P .
DIAMOND AND RELATED MATERIALS, 2004, 13 (02) :241-249
[3]   Preparation of carbon nanotubes over cobalt-containing catalysts via catalytic decomposition of methane [J].
Chai, Siang-Piao ;
Zein, Sharif Hussein Sharif ;
Mohamed, Abdul Rahman .
CHEMICAL PHYSICS LETTERS, 2006, 426 (4-6) :345-350
[4]   Synthesis of Y-junction single-wall carbon nanotubes [J].
Choi, YC ;
Choi, WB .
CARBON, 2005, 43 (13) :2737-2741
[5]  
Dresselhaus M. S., 2001, CARBON NANOTUBES SYN, P113
[6]   Controlled growth of Y-junction nanotubes using Ti-doped vapor catalyst [J].
Gothard, N ;
Daraio, C ;
Gaillard, J ;
Zidan, R ;
Jin, S ;
Rao, AM .
NANO LETTERS, 2004, 4 (02) :213-217
[7]   HELICAL MICROTUBULES OF GRAPHITIC CARBON [J].
IIJIMA, S .
NATURE, 1991, 354 (6348) :56-58
[8]   Synthesis of Y-junction carbon nanotubes within porous anodic aluminum oxide template [J].
Kong, LB .
SOLID STATE COMMUNICATIONS, 2005, 133 (08) :527-529
[9]   Kinetic studies on catalytic decomposition of methane to hydrogen and carbon over Ni/TiO2 catalyst [J].
Zein, SHS ;
Mohamed, AR ;
Sai, PST .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2004, 43 (16) :4864-4870
[10]   COMPLEX BRANCHING PHENOMENA IN THE GROWTH OF CARBON NANOTUBES [J].
ZHOU, D ;
SERAPHIN, S .
CHEMICAL PHYSICS LETTERS, 1995, 238 (4-6) :286-289