IRAS investigation of a catenane adsorption on Au(111)

被引:4
作者
Fustin, CA
Haq, S
Wingen, A
Grégoire, C
Raval, R
Dumas, P
Hannam, JS
Leigh, DA
Rudolf, P
机构
[1] Fac Univ Notre Dame Paix, Lab Interdisciplinaire Spect Elect, B-5000 Namur, Belgium
[2] Univ Liverpool, Surface Sci Res Ctr, Liverpool L69 3BX, Merseyside, England
[3] Orme Merisiers, Synchrotron Soleil, F-91192 Gif Sur Yvette, France
[4] Univ Edinburgh, Sch Chem, Edinburgh EH9 3JJ, Midlothian, Scotland
关键词
infrared reflection absorption spectroscopy (IRAS); catenane; chemisorption;
D O I
10.1016/j.susc.2005.02.021
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The adsorption of a benzylic amide [2]catenane on a Au(1 1 1) single crystal has been studied using infrared reflection absorption spectroscopy. The evolution of the infrared spectra during catenane deposition at different temperatures of the gold substrate (300 and 90 K) has been compared. Evidence of the catenane deformation upon chemisorption have been found at 300 K only. At 90 K the catenane is weakly adsorbed without any deformation. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:57 / 62
页数:6
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