Structural and electrochemical properties of the spinel Li(Mn2-xLix/4Co3x/4)O4

被引：32

作者：

Hong, YS ^{[1
]}

Han, CH

Kim, K

Kwon, CW

Campet, G

Choy, JH

机构：

[1] Korea Univ, Dept Chem, Div Chem & Mol Engn, Seoul 136701, South Korea

[2] Inst Chim Mat Condensee Bordeaux, F-33608 Pessac, France

[3] Seoul Natl Univ, Sch Chem, Natl Nanohybrid Mat Lab, Div Chem & Mol Engn, Seoul 151747, South Korea

[4] Seoul Natl Univ, Ctr Mol Catalysis, Seoul 151747, South Korea

来源：

SOLID STATE IONICS | 2001年 / 139卷 / 1-2期

关键词：

lithium-ion battery; cubic spinel; LiMn2O4;

D O I：

10.1016/S0167-2738(00)00821-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The Li+/Co3+-codoped LiMn2O4 spinel was prepared using two-step synthesis method consisting of solid-state reaction method and citrate modified sol-gel method, in order to investigate the changes of the electrochemical properties of the spinel LiMn2O4 on the amount of Li+/Co3+ ions. The FT-infrared spectra, chemical analysis, and Rietveld refinements of their XRD data revealed that the manganese ions in the 16d sites were replaced by both lithium and cobalt ions. Thus, the composition of obtained powders could be expressed as the new spinel formula (Li)[Mn2-xLix/4Co3x/4]O-4, that is, (Li)[Mn1-3x/23+Mn1+x/24+Lix/4Co3x/43+]O-4. The inclusion of lithium and cobalt ions in 16d sites enhanced the electrochemical cyclability of LiMn2O4 at the expense of a reduction in the initial charge capacity. The improvement in cycling performance was mainly attributed to the suppression of Jahn-Teller distortion as shown in (Li)[Mn2-xLix]O-4 and (Li)[Mn2-xCox]O-4. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：75 / 81

页数：7

共 18 条

[11] RODRIGUEZCARVAJ.J, 1997, PROGRAM FULLPROF VER
[12] The spinel phases LiAlyMn2-yO4 (y = 0, 1/12, 1/9, 1/6, 1/3) and Li(Al,M)1/6Mn11/6O4 (M = Cr, Co) as the cathode for rechargeable lithium batteries
Song, D
Ikuta, H
Uchida, T
Wakihara, M
[J]. SOLID STATE IONICS, 1999, 117 (1-2) : 151 - 156
[13] Improvement in the cycling performance of LiMn2O4 by the substitution of Fe for Mn
Song, MY
Ahn, DS
[J]. SOLID STATE IONICS, 1998, 112 (3-4) : 245 - 248
[14] Novel synthesis process and structural characterization of Li-Mn-O spinels
Takada, T
Enoki, H
Hayakawa, H
Akiba, E
[J]. JOURNAL OF SOLID STATE CHEMISTRY, 1998, 139 (02) : 290 - 298
[15] THE SPINEL PHASE OF LIMN2O4 AS A CATHODE IN SECONDARY LITHIUM CELLS
TARASCON, JM
WANG, E
SHOKOOHI, FK
MCKINNON, WR
COLSON, S
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1991, 138 (10) : 2859 - 2864
[16] THE LI1+XMN2O4/C ROCKING-CHAIR SYSTEM - A REVIEW
TARASCON, JM
GUYOMARD, D
[J]. ELECTROCHIMICA ACTA, 1993, 38 (09) : 1221 - 1231
[17] Lithium-cobalt citrate precursors in the preparation of intercalation electrode materials
Zhecheva, E
Stoyanova, R
Gorova, M
Alcantara, R
Morales, J
Tirado, JL
[J]. CHEMISTRY OF MATERIALS, 1996, 8 (07) : 1429 - 1440
[18] Synthesis and electrochemistry of LiNixMn2-xO4
Zhong, QM
Bonakdarpour, A
Zhang, MJ
Gao, Y
Dahn, JR
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1997, 144 (01) : 205 - 213

← 1 2 →