Chemiluminescence of 3-aminophthalic acid anion-hydrogen peroxide-cobalt (II)

被引：3
作者：
Huang, Kai [1 ]
Sun, Yonghua [1 ]
Liu, Lin [2 ]
Hu, Chaoyu [1 ]
机构：
[1] Chengdu Univ Technol, Coll Mat & Chem & Chem Engn, Mineral Resources Chem Key Lab, Sichuan Higher Educ Inst, Chengdu 610059, Sichuan, Peoples R China
[2] Natl Qual Supervis & Testing Ctr Vanadium & Titan, Panzhihua, Sichuan, Peoples R China
来源：
LUMINESCENCE | 2020年 / 35卷 / 03期
关键词：
3-aminophthalic acid anion; chemiluminescence; singlet oxygen; SENSITIVE DETECTION; SYSTEM; EMISSION;
D O I：
10.1002/bio.3740
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
The 3-aminophthalic acid anion is a light emitter in luminol chemiluminescence. In the present study, the chemiluminescence of the 3-aminophthalic acid anion itself in the presence of hydrogen peroxide-cobalt (II) was studied. The results indicated that 3-aminophthalic acid anion is highly chemiluminescent in the typical hydrogen peroxide-cobalt (II) system. The peak wavelength of this chemiluminescence and the kinetic profile of the 3-aminophthalic acid anion-hydrogen peroxide-cobalt (II) reaction showed similarity with that of luminol, but the chemiluminescence of 3-aminophthalic acid anion had a much lower background signal. In addition, the chemiluminescence mechanism of 3-aminophthalic acid anion-hydrogen peroxide-cobalt (II) was also discussed and speculated as the interaction between 3-aminophthalic acid anion and singlet oxygen.
引用
收藏
页码：400 / 405
页数：6
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