A urea-containing metal-organic framework as a multifunctional heterogeneous hydrogen bond-donating catalyst

被引：18

作者：

Zhu, Chengfeng ^{[1
]}

Tang, Haitong ^{[1
]}

Yang, Keke ^{[1
]}

Wu, Xiang ^{[1
]}

Luo, Yunfei ^{[1
]}

Wang, Jin ^{[1
]}

Li, Yougui ^{[1
]}

机构：

[1] Hefei Univ Technol, Sch Chem & Chem Engn, Anhui Prov Key Lab Adv Catalyt Mat & React Engn, Hefei 230009, Peoples R China

来源：

CATALYSIS COMMUNICATIONS | 2020年 / 135卷

基金：

中国国家自然科学基金;

关键词：

Hydrogen bond-donating catalyst; Heterogeneous catalysis; Metal-organic frameworks; Urea; FRIEDEL-CRAFTS ALKYLATION; INDOLES; NITROALKENES; THIOUREAS; DESIGN; DONORS; ACID; MOFS;

D O I：

10.1016/j.catcom.2019.105837

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A urea-containing metal-organic framework (MOF) was synthesized from a V-shaped dicarboxylate ligand and Cu(II) ions. As the undesirable self-aggregation of the urea moiety has been prohibited in the framework, this MOF can act as a heterogeneous hydrogen bond-donating (HBD) catalyst, which accelerates the cyanosilylation reaction of aldehydes, the Henry reaction of aldehydes, and the methanolysis reaction of epoxides. It also displays a significantly enhanced catalytic activity when compared with its homogeneous urea counterpart and analogous MOF structures.

引用

页数：5

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