A urea-containing metal-organic framework as a multifunctional heterogeneous hydrogen bond-donating catalyst

被引：18

作者：

Zhu, Chengfeng ^{[1
]}

Tang, Haitong ^{[1
]}

Yang, Keke ^{[1
]}

Wu, Xiang ^{[1
]}

Luo, Yunfei ^{[1
]}

Wang, Jin ^{[1
]}

Li, Yougui ^{[1
]}

机构：

[1] Hefei Univ Technol, Sch Chem & Chem Engn, Anhui Prov Key Lab Adv Catalyt Mat & React Engn, Hefei 230009, Peoples R China

来源：

CATALYSIS COMMUNICATIONS | 2020年 / 135卷

基金：

中国国家自然科学基金;

关键词：

Hydrogen bond-donating catalyst; Heterogeneous catalysis; Metal-organic frameworks; Urea; FRIEDEL-CRAFTS ALKYLATION; INDOLES; NITROALKENES; THIOUREAS; DESIGN; DONORS; ACID; MOFS;

D O I：

10.1016/j.catcom.2019.105837

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A urea-containing metal-organic framework (MOF) was synthesized from a V-shaped dicarboxylate ligand and Cu(II) ions. As the undesirable self-aggregation of the urea moiety has been prohibited in the framework, this MOF can act as a heterogeneous hydrogen bond-donating (HBD) catalyst, which accelerates the cyanosilylation reaction of aldehydes, the Henry reaction of aldehydes, and the methanolysis reaction of epoxides. It also displays a significantly enhanced catalytic activity when compared with its homogeneous urea counterpart and analogous MOF structures.

引用

页数：5

共 50 条

[1] Friedel-Crafts Alkylation of Indoles with Nitroalkenes through Hydrogen-Bond-Donating Metal-Organic Framework
Rao, Purna Chandra
Mandal, Sukhendu
CHEMCATCHEM, 2017, 9 (07) : 1172 - 1176
[2] Potential Utilization of Metal-Organic Frameworks in Heterogeneous Catalysis: A Case Study of Hydrogen-Bond Donating and Single-Site Catalysis
Rao, Purna Chandra
Mandal, Sukhendu
CHEMISTRY-AN ASIAN JOURNAL, 2019, 14 (23) : 4087 - 4102
[3] (Thio)urea-Based Covalent Organic Framework as a Hydrogen-Bond-Donating Catalyst
Hu, Jiyun
Zanca, Federica
Lambe, Patricia
Tsuji, Miu
Wijeweera, Samantha
Todisco, Stefano
Mastrorilli, Piero
Shirley, William
Benamara, Mourad
Moghadam, Peyman Z.
Beyzavi, M. Hassan
ACS APPLIED MATERIALS & INTERFACES, 2020, 12 (26) : 29212 - 29217
[4] Microwave-assisted synthesis of urea-containing zirconium metal-organic frameworks for heterogeneous catalysis of Henry reactions
Zhang, He
Gao, Xue-Wang
Wang, Li
Zhao, Xinsheng
Li, Qiu-Yan
Wang, Xiao-Jun
CRYSTENGCOMM, 2019, 21 (09): : 1358 - 1362
[5] Urea-containing metal-organic frameworks for carbonyl compounds sensing
Tehrani, Alireza Azhdari
Abbasi, Hamed
Esrafili, Leili
Morsali, Ali
SENSORS AND ACTUATORS B-CHEMICAL, 2018, 256 : 706 - 710
[6] Urea-Tethered Porous Organic Polymer (POP) as an Efficient Heterogeneous Catalyst for Hydrogen Bond Donating Organocatalysis and Continuous Flow Reaction
Dam, Gourab K.
Let, Sumanta
Jaiswal, Vartika
Ghosh, Sujit K.
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2024, 12 (08): : 3000 - 3011
[7] Turning On Catalysis: Incorporation of a Hydrogen-Bond-Donating Squaramide Moiety into a Zr Metal-Organic Framework
McGuirk, C. Michael
Katz, Michael J.
Stern, Charlotte L.
Sarjeant, Amy A.
Hupp, Joseph T.
Farha, Omar K.
Mirkin, Chad A.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2015, 137 (02) : 919 - 925
[8] Highly Active Urea-Functionalized Zr(IV)-UiO-67 Metal-Organic Framework as Hydrogen Bonding Heterogeneous Catalyst for Friedel-Crafts Alkylation
Das, Aniruddha
Anbu, Nagaraj
Mostakim, S. K.
Dhakshinamoorthy, Amarajothi
Biswas, Shyam
INORGANIC CHEMISTRY, 2019, 58 (08) : 5163 - 5172
[9] Highly Active La(III)-Based Metal-Organic Framework as a Heterogeneous Lewis Acid Catalyst for Friedel-Crafts Alkylation
Wu, Jia-Qi
Wu, Xin-Yuan
Lu, Jian-Mei
Shi, Qian
Shao, Li-Xiong
CHEMISTRY-A EUROPEAN JOURNAL, 2022, 28 (69)
[10] Gold Nanoparticles Incorporated in a Zinc-Based Metal-Organic Framework as Multifunctional Catalyst for the Oxygen Reduction and Hydrogen Evolution Reactions
Yadav, Dharmendra K.
Gupta, Rupali
Ganesan, Vellaichamy
Sonkar, Piyush K.
Yadav, Mamta
CHEMELECTROCHEM, 2018, 5 (18): : 2612 - 2619

← 1 2 3 4 5 →