A 1:4 adduct of tetrachlorobis(mu-phenylimido)dizirconium(IV) and tetrahydrofuran

被引:5
作者
Polamo, M
Mutikainen, I
Leskela, M
机构
[1] Inorganic Chemistry Laboratory, Department of Chemistry, University of Helsinki, FIN-00014 Helsinki
关键词
D O I
10.1107/S0108270195016891
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The title complex, bis(mu-phenylimido)bis[dichlorobis-(tetrahydrofuran)zinc], [Zr2Cl4(C6H5N)(2)(C4H8O)(4)], contains two octahedral Zr-IV ions which are connected by two bridging phenylimido ligands. The Zr coordination polyhedra have significantly different geometries. In one, the chloro ligands are cis, while in the other they take up trans positions. Both Zr-IV ions are situated on a twofold axis.
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页码:1082 / 1084
页数:3
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