Catalytic reforming of oxygenated hydrocarbons for hydrogen with low levels of carbon monoxide

被引:109
作者
Davda, RR [1 ]
Dumesic, JA [1 ]
机构
[1] Univ Wisconsin, Dept Chem Engn, Madison, WI 53706 USA
关键词
D O I
10.1002/anie.200351664
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Vaporization of water leads to low levels of CO: Now, it is possible to produce low-CO-containing, H2-rich streams by simple, aqueous-phase reforming of oxygenates. The schematic of ethylene glycol reforming on a Pt catalyst shows the composition of a gas bubble in the aqueous-phase reactor. Lowering the H2 and CO2 pressures, by increasing the water pressure, lowers the CO concentration in the product. WGS = water-gas shift.
引用
收藏
页码:4068 / 4071
页数:4
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