Catalytic reforming of oxygenated hydrocarbons for hydrogen with low levels of carbon monoxide

被引:109
作者
Davda, RR [1 ]
Dumesic, JA [1 ]
机构
[1] Univ Wisconsin, Dept Chem Engn, Madison, WI 53706 USA
关键词
D O I
10.1002/anie.200351664
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Vaporization of water leads to low levels of CO: Now, it is possible to produce low-CO-containing, H2-rich streams by simple, aqueous-phase reforming of oxygenates. The schematic of ethylene glycol reforming on a Pt catalyst shows the composition of a gas bubble in the aqueous-phase reactor. Lowering the H2 and CO2 pressures, by increasing the water pressure, lowers the CO concentration in the product. WGS = water-gas shift.
引用
收藏
页码:4068 / 4071
页数:4
相关论文
共 13 条
  • [11] Conversion of hydrocarbons and alcohols for fuel cells
    Rostrup-Nielsen, JR
    [J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2001, 3 (03) : 283 - 288
  • [12] Aqueous-phase reforming of methanol and ethylene glycol over alumina-supported platinum catalysts
    Shabaker, JW
    Davda, RR
    Huber, GW
    Cortright, RD
    Dumesic, JA
    [J]. JOURNAL OF CATALYSIS, 2003, 215 (02) : 344 - 352
  • [13] Van Keulen A.N.J., 2001, US Patent, Patent No. 6207307